Low equivalent weight ionomer

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C526S213000, C526S242000, C204S296000

Reexamination Certificate

active

08071702

ABSTRACT:
An ionomer and a process for forming the ionomer such that the ionomer has (1) low equivalent weight (below 950, preferably between 625 and 850, and most preferably between 675 and 800) and (2) high conductivity (greater than 0.13 S/cm). In another embodiment, the invention is an ionomer having (1) low equivalent weight (below 950, preferably between 625 and 850, and most preferably between 675 and 800) and (2) acceptably low hydration (less than about 120 weight percent). These ionomers are capable of being processed into thin film and are extremely well-suited for low humidity or high temperature fuel cell applications.

REFERENCES:
patent: 3282875 (1966-11-01), Connolly et al.
patent: 3291843 (1966-12-01), Fritz et al.
patent: 3692569 (1972-09-01), Grot
patent: 4358545 (1982-11-01), Ezzell et al.
patent: 4417969 (1983-11-01), Ezzell et al.
patent: 4478695 (1984-10-01), Ezzell et al.
patent: 4661411 (1987-04-01), Martin et al.
patent: 4940525 (1990-07-01), Ezzell et al.
patent: 5082472 (1992-01-01), Mallouk et al.
patent: 5246792 (1993-09-01), Watanabe
patent: 5264508 (1993-11-01), Ishibe et al.
patent: 5281680 (1994-01-01), Grot
patent: 5393852 (1995-02-01), Ishibe et al.
patent: 5463005 (1995-10-01), Desmarteau
patent: 5547551 (1996-08-01), Bahar et al.
patent: 5599614 (1997-02-01), Bahar et al.
patent: 5608022 (1997-03-01), Nakayama et al.
patent: 5654109 (1997-08-01), Plowman et al.
patent: 5718947 (1998-02-01), Martin et al.
patent: 5981097 (1999-11-01), Rajendran
patent: 5989741 (1999-11-01), Bloomfield et al.
patent: 6046271 (2000-04-01), Wu et al.
patent: 6054230 (2000-04-01), Kato
patent: 6156451 (2000-12-01), Banerjee et al.
patent: 6255536 (2001-07-01), Worm et al.
patent: RE37307 (2001-08-01), Bahar et al.
patent: 6294612 (2001-09-01), O'Brien
patent: 6576100 (2003-06-01), Arcella et al.
patent: 2001/0033986 (2001-10-01), Isobe et al.
patent: 606842 (1994-07-01), None
patent: 1 179 548 (2002-02-01), None
patent: 1034197 (1966-06-01), None
patent: 6-234816 (1994-08-01), None
patent: WO 90/15828 (1990-12-01), None
patent: WO 94/03503 (1994-02-01), None
patent: WO 99/52954 (1999-10-01), None
patent: WO 00/24709 (2000-05-01), None
patent: WO 00/52060 (2000-09-01), None
patent: WO 00/79629 (2000-12-01), None
patent: WO 02/43171 (2002-05-01), None
patent: WO-03/050150 (2003-06-01), None
patent: WO-03/050151 (2003-06-01), None
“Perfluorinated Resinsulfonic Acid (Nafion-H) Catalysis in Synthesis”, by G. Olah, P. Iyer, and P. Surya, in Journal: Synthesis (Stuttgart), 1986 (7) 513-531 (Translation).
“Perfluorinated Resin Sulfonic Acid (Nafion-H) Catalysis in Organic Synthesis” by T. Yamato in Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry, vol. 53, No. 6, Jun. 1995, pp. 487-499.
“The Use of Nafion 415 Membrane in Copper Electrowinning from Chloride Solution” by R. Raudsepp and M. Vreugde, in CIM Bulletin, 1982 V75, N842, P122.
“Mini-Emulsion Polymerization” by E. David Sudol and Mohamed S. El-Aasser, in “Emulsion Polymerization and Emulsioin Polymers,” P. A. Lowell and M.S. El-Aaser, John Wiley and Sons, Ltd., New York 1997, p. 700-709.
“Characterization of Polymer Electrolytes for Fuel Cell Applications,” T. Zawodzinski, T. Springer, F. Uribe and S. Gottesfeld, Solid State Ionics, vol. 60, p. 199 (1993).
“Investigation of the Proton Transport in Nafioni Membranes as a Function of Direction, Temperature and Relative Humidity,” G. Blumenthal, M. Cappadonia, and M. Lehmann, Ionics, vol. 2, p. 102-106 (1996).
“Chemical and Morphological Properties of Solution-Cast Perfluorosulfonate Ionomers,” by R. Moore and C. Martin, Macromolecules, vol. 21, No. 5, 1988, p. 1334-1339.
“Morphology and Chemical Properties of the Dow Perfluorosulfonate Ionomers,” R. Moore and C. Martin, Macromolecules 1989, vol. 22, pp. 3594-3599 (1989).
“Water Uptake by and Transport Through Nafion 117 Membranes,” T. Zawodzinski, C. Derouin, S. Radzinski, R. Sherman. V. Smith, T.Springer, and S. Gottesfeld, Journal of the Electrochemical Society, vol. 140, No. 4, 1041-1047.
Product Literature from Perma Pure, Inc., Toms River, NJ copyright 2000.
“Perfluorosulphonic Acid (Nafion) Membrane as a Separator for an Advanced Alkaline Water Elecrolyser,” R. Yen, J. McBreen, G. Kissel, F. Kulesa, and S. Srinivasan, Journal of Applied Electrochemistry, vol. 10 (1980), p. 741-747.
Product Literature on Nafion from Du Pont Flurorproducts, Fayetteville, NC 28306 (Sep. 2001).
“Uber Erstarrungs und Quellungserscheinungen von Gelatine,” Paul Schroeder, Z. Physik Chem., Vo. 75 (1903) , p. 75.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Low equivalent weight ionomer does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Low equivalent weight ionomer, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Low equivalent weight ionomer will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-4304007

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.