Method for producing fluorinated organic compounds

Organic compounds -- part of the class 532-570 series – Organic compounds – Halogen containing

Reexamination Certificate

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C570S135000, C570S157000, C570S164000, C570S179000, C570S188000

Reexamination Certificate

active

08067649

ABSTRACT:
Disclosed is a process for producing tetrafluoropropene comprising: (a) catalytically fluorinating at least one tetrafluoropropene in a first reactor to produce HCFO-1233xf; (b) reacting said HCFO-1233xf with hydrogen fluoride in a second reactor to produce HCFC-244bb; (c) recycling at least a portion of said HCFC-244bb back to said first reactor as recycled HCFC-244bb; and (d) catalytically dehydrochlorinating said recycled HCFC-244bb in said first reactor to produce HFO-1234yf.

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R. Eric Banks et al., Preparation of 2,3,3,3-tetrafluoropropene From Trifluoroacetylacetone and Sulphur Tetrafluoride, Journal of Fluorine Chemistry, vol. 82 (1997), pp. 171-174. US.
Knunyants,I.L., et al.: “Reactions of Fluoro Olefins. XIII. Catalytic Hydrogenation of Perfluoro Olefins.”: Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya 1412-18 CODEN: IASKA6; ISSN: 0002-3353, 1960, XP002548816—pp. 1313, 1316.

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