Process for preparing hydroxyalkyl(meth) acrylates using...

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

Reexamination Certificate

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C560S093000, C560S200000

Reexamination Certificate

active

07659425

ABSTRACT:
The present invention relates to a process for preparing hydroxyalkyl (meth)acrylates by reacting at least one compound A which contains at least one epoxide group with at least one compound B which contains at least one carboxylic acid group, wherein A and/or B also contains at least one (meth)acrylate group, in the presence of Lewis acid catalysts, each of which contains at least one directly bonded di(cyclo)alkylamino group.

REFERENCES:
patent: 4069242 (1978-01-01), Gurgiolo
patent: 4126527 (1978-11-01), Kaufman
patent: 6153788 (2000-11-01), Fischer et al.
patent: 6617413 (2003-09-01), Bruchmann et al.
patent: 1 480 945 (1977-07-01), None
Database CA [Online] Chemical Abstracts Service, Columbus, Ohio, US; Kimura, Kaoru et al: “Acrylate and methacrylate esters” XP002381405 gefunden im STN Database accession No. 1977:73371 * Zusammenfassung * & JP 51 086413 A (Toa Gosei Chemical Industry Co., Ltd., Japan) Jul. 29, 1976.
Analytical Sciences, vol. 17, Nov. 2001, pp. 1295-1299, Morikatsu Matsunaga et al, “Optimization of Conditions for Detailed Compositional Analysis of Acrylic Oligomers by Supercritical Fluid Chromatography with Temperature Programming or Modifier Gradient Technique”.
Polymer, vol. 37, No. 20, (month unavailable) 1996, pp. 4629-4631, Michael A. Beckett et al, “Polymer Communications—A convenient n.m.r. method for the measurement of Lewis acidity at boron centres: correlation of reaction rates of Lewis acid initiated epoxide polymerizations with Lewis acidity”.

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