Synthesis of ITQ-12

Chemistry of inorganic compounds – Zeolite – Organic compound used to form zeolite

Reexamination Certificate

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C423S718000

Reexamination Certificate

active

07837979

ABSTRACT:
A process for synthesizing the porous crystalline material ITQ-12 is disclosed and employs an organic directing agent having the formula:where n is an integer from 1 to 3 and Q−is an anion. The resultant ITQ-12 is useful in as a catalyst in chemical conversion reactions and as an adsorbent for gas separation.

REFERENCES:
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patent: 6471939 (2002-10-01), Boix et al.
Zicovich-Wilson et al, “Structure, Vibrational Analysis, and Insights into Hose-Guest Interactions in As-Synthesized Pure Silica ITQ-12 Zeolite by Periodic B3LYP Calculations”, J.Am.Chem.Soc. (2007), 129, pp. 11512-11523.
Loiseau et al, “Crystalline oxyfluorinated open-framework compounds: Silicates, metal phosphates, metal fluorides and metal-organic frameworks”, Journal of Fluorine Chemistry, 128, 2007, pp. 412-422, (Sep. 2006).
Olson, David H.; Yang, Xiaobo; Camblor, Miguel A.; ITQ-12: A Zeolite Having Temperature Dependent Adsorption Selectivity and Potential for Propene Seperation, J. Phys. Chem. B 2004, 108, 11044-11048.

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