Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof
Reexamination Certificate
2005-02-10
2010-06-15
Qazi, Sabiha (Department: 1612)
Organic compounds -- part of the class 532-570 series
Organic compounds
Carboxylic acids and salts thereof
Reexamination Certificate
active
07737299
ABSTRACT:
In the production of 2,2,3,3-tetrafluorooxethane by reaction of tetrafluoroethylene with a compound of formaldehyde generation source in anhydrous hydrogen fluoride, the reaction is carried out in the presence of polyfluoroalkylcarboxylic acid or polyfluoroalkyl ester thereof, represented by the following general formula RfCOORf′ (where Rf is a polyfluoroalkyl group having 1-5 carbon atoms, and Rf′ is a hydrogen atom or a polyfluoroalkyl group having 1-5 carbon atoms), preferably CF3COOH, CF3COOCH2CF2CF3, or CF3COOCH2CF3, whereby a high reaction yield can be attained.
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Weinmayr, “Hydrogen Fluoride as a Condensing Agent. VI. Reactions of Fluoroolefins with Formaldehyde Hydrogen Fluoride,” JOC 28 pp. 492-494 (1963).
Ikeda Sunao
Sonoi Takehiro
Brinks Hofer Gilson & Lione
Qazi Sabiha
Unimatec Co. Ltd.
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