Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By addition of entire unsaturated molecules – e.g.,...
Patent
1995-01-13
1996-09-17
Mc Farlane, Anthony
Chemistry of hydrocarbon compounds
Unsaturated compound synthesis
By addition of entire unsaturated molecules, e.g.,...
585528, 585529, 585530, 585531, C07C 202, C07C 208
Patent
active
055570275
ABSTRACT:
The present invention relates to a catalyst suitable for oligomerization of olefins which is prepared by a process which comprises reacting a catalyst precursor ligand having a formula ##STR1## wherein R.sub.1 and R.sub.2 each independently is an alkyl, alkoxy, aryl, or aryloxy group having from about 1 to about 20 carbon atoms, with the proviso that R.sub.1 and R.sub.2 are not both aryl, or R.sub.1 and R.sub.2 together form a divalent hydrocarbon moiety, and X is 1,2-arylene, O-CH.sub.2, S-CH.sub.2, or Se-CH.sub.2 with a deprotonation source, a transition metal compound and a catalyst activator. The invention further relates to an oligomerization process utilizing this catalyst.
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J. Am. Chem. Soc. 1981, 1234-1235, "A Stable Monocyclic Triarylalkoxy P-H Phosphorane, a 10-P-5 Species with an Apical P-H Bond, and It's Conjugate Base, a Phosphoramide", Michael R. Ross and J. C. Martin.
Irzinski E. D.
Mc Farlane Anthony
McCollough Pamela J.
Shell Oil Company
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