Method for the production of polymethacrylates

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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C08F 200

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048372862

ABSTRACT:
Improved method for the production of polymethacrylates by a rapid polymerization, which comprises polymerizing an unsaturated monomer selected from a methacrylate and a monomer mixture comprising predominantly a methacrylate which may partially contain a polymer of the monomer (i.e. a syrup of the monomer or monomer mixture) in the presence of a radical polymerization initiator, a reducing compound containing sulfur in the molecule thereof, a copper-containing compound and a specific tertiary amine hydrohalogenate or a quaternary ammonium halide. Said polymethacrylates can give molded products having excellent mold release characteristics and are useful particularly for the production of optical parts such as conventional lenses, Fresnel's lens, optical recording disc media, prisms, mirrors, etc.

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