Suppressed chromatography and salt conversion system

Liquid purification or separation – With means to add treating material – Chromatography

Reexamination Certificate

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C210S656000, C210S638000, C210S195100, C210S663000, C436S150000, C422S070000, C204S632000

Reexamination Certificate

active

07618535

ABSTRACT:
Method and apparatus for suppressed ion analysis in which a sample solution of analyte (e.g., anion) in an eluent of electrolyte counterions (e.g., sodium), is chromatographically separated. Then, the counterions are suppressed in a suppression zone and removed and used to convert the analyte ions to salt form in a salt-converting zone. The suppression and salt-converting zones may be contiguous or remote, and may be performed in devices of the membrane suppresser type. Thereafter, the salts or acids or bases formed from them (e.g., in membrane suppressor devices) are detected. Also, salt conversion can be performed using two ion exchange packed bed salt convertors in which one bed is on-line while the other is regenerated, followed by a reversal of flow.

REFERENCES:
patent: 3897213 (1975-07-01), Stevens et al.
patent: 3920397 (1975-11-01), Small et al.
patent: 3925019 (1975-12-01), Small Hamish et al.
patent: 3926559 (1975-12-01), Stevens
patent: 4265634 (1981-05-01), Pohl
patent: 4455233 (1984-06-01), Pohl et al.
patent: 4474664 (1984-10-01), Stevens et al.
patent: 4751004 (1988-06-01), Stevens et al.
patent: 4751189 (1988-06-01), Rocklin
patent: 4794088 (1988-12-01), Miyaki et al.
patent: 4861555 (1989-08-01), Mowery, Jr.
patent: 4999098 (1991-03-01), Pohl et al.
patent: 5045204 (1991-09-01), Dasgupta et al.
patent: 5068090 (1991-11-01), Connolly
patent: 5352360 (1994-10-01), Stillian et al.
patent: 5597734 (1997-01-01), Small et al.
patent: 5773615 (1998-06-01), Small et al.
patent: 6328885 (2001-12-01), Srinivasan et al.
patent: 6436719 (2002-08-01), Srinivasan et al.
patent: 6752927 (2004-06-01), Srinivasan et al.
patent: 6808608 (2004-10-01), Srinivasan et al.
patent: 7473354 (2009-01-01), Liu et al.
patent: 7517696 (2009-04-01), Srinivasan et al.
patent: 1 074 837 (2001-02-01), None
patent: WO 94/18555 (1994-08-01), None
patent: WO 99/44054 (1999-09-01), None
Berglund et al., “Two-Dimensional Conductometric Detection in Ion Chromatography. Postsuppressor Conversion of Eluite Acids to a Salt,”Anal. Chem.64:3007-3012 (1992).
Berglund et al., “Two-Dimensional Conductometric Detection in Ion Chromatography. Postsuppressor Conversion of Eluite Acids to a Base,”Anal. Chem.63:2175-2183 (1991).
Caliamanis et al., “Conductometric Detection of Anions of Weak Acids in Chemically Suppressed Ion Chromatography,”Anal. Chem.,69:3272-3276 (1997).
Cassidy et al., “Performance of Annular Membrane and Screen-Tee Reactors for Postcolumn-Reaction Detection of Metal Ions Separated by Liquid Chromatography,” Anal. Chem. 59:85-90, (1987).
Dasgupta, “Approaches to Ionic Chromatography,”Ion Chromatography, Tarter, J.G., Ed., Marcel Dekker, Inc., New York, 1987, pp. 220-224.
Gupta et al., “Advances in Membrane Suppressors for Ion Chromatography,”J. Chromatogr. Sci.26:34-38, (1988).
Huang et al., “Conductometric Detection of Anions of Very Weak Acids by Incomplete Suppressed Ion Chromatography,”J. Chromatography, A 832:141-148 (1999).
Morris et al., “How to Make Simple High-Pressure Connection Using Polymeric Capillary Tubing,”LCGC, 10(2):149, (1992).
Murayama et al., “Peak Enhancement of Carboxilic Acids ion Ion-Exclusion Chromatography with Cation Exchange Hollow-Fiber Suppressor Using Neutral and Alkaline Enchancers,”J. Chromatogr., 435:417-424, (1988).
Renn et al., “Examination of Automated Solute-Independent Calibration Technique,”Anal. Chem.,61:1915-1921, (1989).
Strong et al., “Electrodialytic Eluent Production and Gradient Generation in Ion Chromatography,”Anal. Chem., 63:480- 486 (1991).
Strong et al., “Electrodialytic Membrane Suppressor for Ion Chromatography,”Anal. Chem., 61:939-945, (1989).
Synovec et al., “Ratio of Sequential Chromatograms for Quantitative Analysis and Peak Deconvulation: Application to Standard Addition Method and Process Monitoring,”Anal. Chem., 62:1597-1603, (1990).
Tanaka and Fritz,“Determination of Bicarbonate by Ion-Exclusion Chromatography with Ion-Exchange Enhancement of Conductivity Detection,”Anal. Chem., 59:708-712 (1987).
Tanaka and Fritz, “Separation of Aliphatic Carboxylic Acids in Ion-Exclusion Chromatography Using a Weak-Acid Eluent,”J. Chromatogr., 361:151-160, (1986).
Wilson et al., “Quantitative Ion Chromatography Without Standards b Conductivity Detection,”Anal. Chem., 56:1457-1460, (1984).
Yan et al., “indirect Suppressed-Conductivity Ion Chromatography,”LCGC, 18(2):200-204, (Feb. 2000).
Zumdhal, S.ChemistryD.C. Health and Company, pp. 44, 592-594, (1986).

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