Process for the copolymerization of ethylene

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

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C526S171000, C526S348600, C526S348500, C526S348000, C526S943000, C526S901000, C526S941000, C556S053000

Reexamination Certificate

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07615597

ABSTRACT:
A process for producing a polymer of ethylene containing from 0.1 to 99% by mol of one or more derived units of alpha-olefins and optionally from 0 to 5% by mol polyene, comprising contacting ethylene, one or more alpha-olefins and optionally said polyene, in the presence of a catalyst system obtainable by contacting:a) a metallocene compound of formula (I):whereinM is zirconium, hafnium or titanium; X, is a hydrogen atom, a halogen atom, or a hydrocarbon group; R1is a hydrocarbon group;R2, R3, R4and R5are hydrogen atoms, or hydrocarbon groups; R6is a hydrocarbon group; L is a divalent bridging group, and T is a divalent radical of formula (II) or (III):whereinR8and R9are hydrogen or hydrocarbon groups; andb) an alumoxane or a compound capable of forming an alkyl metallocene cation.

REFERENCES:
patent: 5145819 (1992-09-01), Winter et al.
patent: 5280074 (1994-01-01), Schreck et al.
patent: 5753769 (1998-05-01), Ueda et al.
patent: 5753773 (1998-05-01), Langhauser et al.
patent: 5770753 (1998-06-01), Küber et al.
patent: 5786432 (1998-07-01), Küber et al.
patent: 5830821 (1998-11-01), Rohrmann et al.
patent: 5840644 (1998-11-01), Küber et al.
patent: 5854354 (1998-12-01), Ueda et al.
patent: 5969049 (1999-10-01), Ueda et al.
patent: 6051727 (2000-04-01), Küber et al.
patent: 6096841 (2000-08-01), Sacchetti et al.
patent: 6191294 (2001-02-01), Resconi et al.
patent: 6242544 (2001-06-01), Küber et al.
patent: 6255506 (2001-07-01), Küber et al.
patent: RE37384 (2001-09-01), Winter et al.
patent: 6306996 (2001-10-01), Cecchin et al.
patent: 6383969 (2002-05-01), Francois et al.
patent: 6444833 (2002-09-01), Ewen et al.
patent: 6451726 (2002-09-01), Zambon et al.
patent: 6469114 (2002-10-01), Schottek et al.
patent: 6482902 (2002-11-01), Bohnen et al.
patent: 6492465 (2002-12-01), Burkhardt et al.
patent: 6492539 (2002-12-01), Bingel et al.
patent: 6608224 (2003-08-01), Resconi et al.
patent: 6627764 (2003-09-01), Schottek et al.
patent: 6635779 (2003-10-01), Ewen et al.
patent: 6723865 (2004-04-01), Evain et al.
patent: 6797794 (2004-09-01), Zambon et al.
patent: 6841501 (2005-01-01), Resconi et al.
patent: 6870016 (2005-03-01), Burkhardt et al.
patent: 6878786 (2005-04-01), Resconi et al.
patent: 6930190 (2005-08-01), Nifant'ev et al.
patent: 6987196 (2006-01-01), Resconi et al.
patent: 7009015 (2006-03-01), Evain et al.
patent: 7019157 (2006-03-01), Uwai et al.
patent: 7022793 (2006-04-01), Galimberti et al.
patent: 7041750 (2006-05-01), Covezzi et al.
patent: 7074864 (2006-07-01), Resconi
patent: 7109278 (2006-09-01), Okumura et al.
patent: 7115761 (2006-10-01), Resconi et al.
patent: 7122498 (2006-10-01), Hart et al.
patent: 7141637 (2006-11-01), Elder et al.
patent: 7183332 (2007-02-01), Ferraro et al.
patent: 7297747 (2007-11-01), Hart et al.
patent: 2002/0107344 (2002-08-01), Peterson
patent: 2003/0008984 (2003-01-01), Kratzer et al.
patent: 2003/0013913 (2003-01-01), Schottek et al.
patent: 2003/0149199 (2003-08-01), Schottek et al.
patent: 2004/0192931 (2004-09-01), Nifant'ev et al.
patent: 2005/0192418 (2005-09-01), Ewen et al.
patent: 2006/0020096 (2006-01-01), Schottek et al.
patent: 2006/0094840 (2006-05-01), Resconi et al.
patent: 2006/0167195 (2006-07-01), Resconi et al.
patent: 2006/0252637 (2006-11-01), Okumura
patent: 2006/0287436 (2006-12-01), Pelliconi et al.
patent: 2007/0060727 (2007-03-01), Pelliconi et al.
patent: 2007/0117940 (2007-05-01), Suhm et al.
patent: 2007/0149729 (2007-06-01), Resconi
patent: 2007/0276095 (2007-11-01), Resconi et al.
patent: 2007/0299208 (2007-12-01), Resconi et al.
patent: 19903306 (2000-08-01), None
patent: 19917985 (2000-10-01), None
patent: 19962814 (2001-06-01), None
patent: 19962910 (2001-07-01), None
patent: 129 368 (1984-12-01), None
patent: 172 961 (1986-03-01), None
patent: 353 318 (1990-02-01), None
patent: 0633272 (1995-01-01), None
patent: 697 418 (1996-02-01), None
patent: 0775707 (1997-05-01), None
patent: 846 696 (1998-06-01), None
patent: 1 308 466 (2003-05-01), None
patent: 03126704 (1991-05-01), None
patent: 06026804 (1994-02-01), None
patent: 9102012 (1991-02-01), None
patent: 9200333 (1992-01-01), None
patent: 9532995 (1995-12-01), None
patent: 98/22486 (1998-05-01), None
patent: 9921899 (1999-05-01), None
patent: 99/36427 (1999-07-01), None
patent: 99/40129 (1999-08-01), None
patent: 99/45043 (1999-09-01), None
patent: 0121674 (2001-03-01), None
patent: 01/44318 (2001-06-01), None
patent: 01/46272 (2001-06-01), None
patent: 0144318 (2001-06-01), None
patent: 01/48034 (2001-07-01), None
patent: 01/62764 (2001-08-01), None
patent: 0162764 (2001-08-01), None
patent: 02/02659 (2002-01-01), None
patent: 02/083699 (2002-10-01), None
patent: 02100908 (2002-12-01), None
patent: 02100909 (2002-12-01), None
patent: 03/014107 (2003-02-01), None
patent: 03045964 (2003-05-01), None
patent: 03070778 (2003-08-01), None
patent: 2004/005360 (2004-01-01), None
patent: 2004/033510 (2006-07-01), None
A. Rossi et al., “End Groups in 1-Butene Polymerization via Methylaluminoxane and Zirconocene Catalyst,”Macromolecules, vol. 28(6), pp. 1739-1749 (1995).
N. Naga et al., “Effect of co-catalyst system on α-olefin polymerization withrac-andmeso-[dimethylsilylenebis(2,3,5-trimethylcyclopentadieny1)]zirconium dichloride,”Macromol, Rapid Commun., vol. 18, pp. 581-589 (1997).
M. Vathauer et al., “Homopolymerizations of α-Olefins with Diastereomeric Metallocene/MAO Catalysts,” vol. 33(6), pp. 1955-1959 (2000).
U.S. Appl. No. 11/376,406, filed Mar. 15, 2006, Resconi.
U.S. Appl. No. 11/376,409, filed Mar. 15, 2006, Resconi.
C. Carman et al., “Monomer Sequence Distribution in Ethylene-Propylene Rubber Measured by13C NMR. 3. Use of Reaction Probability Model,”Macromolecules, vol. 10(3), pp. 536-544 (1977).
V. Busico et al., “Regiospecificty of 1-butene polymerization catalyzed by C2-symmetric group IV metallocenes,”Macromol. Rapid Commun., vol. 16, pp. 269-274 (1995).
L Ewen et al., “ChiralAnsaMetallocenes with Cp Ring-Fused to Thiophenes and Pyrroles: Syntheses, Crystal Structures, and Isotactic Polypropylene Catalysts,”J. Am. Chem. Soc., vol. 123(20), pp. 4763-4773 (2001) XP-002233282.

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