Preparation of haloperfluoro and perfluoro ethers

Details Preparation of haloperfluoro and perfluoro ethers Preparation of haloperfluoro and perfluoro ethers

1994-01-18

1995-09-12

Killos, Paul J.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic halides

568615, C07C 5158

Patent

active

054498252

ABSTRACT:
Process for preparing haloperfluoro and perfluoro ethers wherein a metal halide is reacted with a 3-haloperfluoropropene oxide to obtain a 2,3-dihaloperfluorocarbonyl fluoride; a metal halide, 2,3-dihaloperfluorocarbonyl fluoride and 3-haloperfluoropropene oxide are reacted to obtain a 2-(2',3'-dihaloperfluoropropoxy)-3-haloperfluoropropionyl fluoride; 2-(2',3'-dihaloperfluoropropoxy)-3-haloperfluoropropionyl fluoride is decarboxylated and dehalogenated to obtain perfluorovinylallylether. Alternatively, 2-(2',3'-dihaloperfluoropropoxy)-3-haloperfluoropropionyl fluoride is reacted with metal halide and 3-haloperfluoropropene oxide to obtain a 2-[2'-(2",3"-dihaloperfluoropropoxy)-3'-haloperfluoropropoxy]-3-haloperflu oropropionyl fluoride, or a higher polyether, and 2-[2'-(2",3"-dihaloperfluoropropoxy)-3'-haloperfluoropropoxy]-3-haloperflu oropropionyl fluoride or the polyether is decarboxylated and dehalogenated to obtain a 3,6-dioxa-5-halodifluoromethylperfluoronona-1,8-diene or the corresponding polyether.

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CA 113:131538 1990.

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