Process for the extraction of specific transition metals...

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Group vib metal

Reexamination Certificate

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C423S062000, C423S138000, C423S154000, C502S038000, C502S050000

Reexamination Certificate

active

07604784

ABSTRACT:
A process is disclosed for separation and recovery of vanadium, molybdenum, iron, tungsten, cobalt and nickel from alumina-based materials, mattes, ores, manufacturing by-products and waste. These elements are oxidized. The oxides are reacted with gaseous HCl to form volatile chloride-bearing compounds that subsequently sublimate. The volatile compounds are condensed in a downward-stepped thermal gradient that allows collection of moderate to high purity compounds of individual elements with exception of a nickel-cobalt co-condensate. Nickel is separated from cobalt by precipitation of nickel chloride from concentrated HCl pressurized with gaseous HCl.

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Zeng, Li, Cheng, Chu Young, A literature review of the recovery of the molybdenum and vanadium from spent hydrodesulphurization catalysts. Part I: Metallurgical processes,Hydrometallurgy(2009), doi: 10.1016/j.hydromet.2009.03.010.
Zeng, Li, Cheng, Chu Young, A literature review of the recovery of molybdenum and vanadium from spent hydrodesulphurization catalysts. Part II: Separation and purification,Hydrometallurgy(2009), doi: 10.1016/j.hydromet.2009.03.012.

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