Ruthenium complexes with tridentate heterocyclic ligand and...

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

Reexamination Certificate

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C136S252000, C136S263000, C556S137000

Reexamination Certificate

active

07615636

ABSTRACT:
A ruthenium complex is provided. The ruthenium complex is represented by the following Formula (I):in which, X is a monodentate anion ligand, R1, R2, R4and R5are the same or different substituents and represent alkyl, alkoxy, aminoalkyl, haloalkanes or substituted phenyl group, carboxylic acid group or acid radical salt thereof, sulfonic acid group or acid radical salt thereof, phosphoric acid group or acid radical salt thereof or hydrogen atom. R3represents perhalogenated alkyl group, alkoxy, alkyl, amino, halogens, or hydrogen atom. The ruthenium complexes are suitable for being used as dye-sensitizers for fabricating dye-sensitized solar cells.

REFERENCES:
patent: 6639073 (2003-10-01), Islam et al.
patent: 98/50393 (1998-11-01), None
Article titled “Engineering of Efficient Panchromatic Sensitizers for Nanocrystalline TiO2-Based Solar Cells” jointly authored by Nazeeruddin et al., J. Am. Chem. Soc. 2001, 123, pp. 1613-1624.
Article titled “Conversion of Light to Electricity by cis-X2Bis(2,2′-bipyridyl-4,4′-dicarboxylate)ruthenium(II) Charge-Transfer Sensitizers (X=Cl−, I−, CN−, and SCN−) on Nanocrystalline TiO2 Electrodes” jointly authored by Nazeeruddin et al., , J. Am. Chem. Soc. 1993, 115, pp. 6382-6390.

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