Method for the recovery of valuable metals and arsenic from...

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Group ib metal

Reexamination Certificate

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C423S023000, C423S027000, C423S034000, C423S037000, C423S042000, C423S043000, C423S087000

Reexamination Certificate

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07615199

ABSTRACT:
The invention relates to a method for the treatment of material containing at least one valuable metal and arsenic to form a valuable metal-depleted scorodite sediment and a pure aqueous solution to be discharged from the process. According to the method, the valuable metals are first removed from the material to be treated and then arsenic precipitation from the solution is performed in two stages. By means of the method, the aim is to obtain as low a valuable metal content as possible in the scorodite sediment that will be formed. Likewise, the arsenic and valuable metal content of the aqueous solution that is formed during arsenic precipitation also remains so low that the water can be released into the environment.

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patent: 7314604 (2008-01-01), Harvey et al.
patent: 2384664 (2001-04-01), None
Wang et al, “Arsenic fixation in metallurgical plant effluents in the form of crystalline scorodite via a non-autoclave oxidation-precipitation process”, Mar. 1, 2000, Annual Meeting for the Society for Mining, Metallurgy and Exploration, pp. 225-237.
Q. Wang et al., “Arsenic Fixation in Metallurgical Plant Effluents in the Form of Crystalline Scorodite via a Non-Autoclave Oxidation-Precipitation Process”, Minor Elements 2000, pp. 225-237, Society for Mining, Metallurgy, and Exploration, Inc.
W. Qiankun et al., “A Novel Hydrometallurgical Process for the Immobilization of Arsenic”, Proceedings of the Third International Conference on Hydrometallurgy, Kunming, China, Nov. 1998, pp. 543-553, International Academic Publishers, The People's Republic of China.
G.P. Demopoulos et al., “Options for the Immobilization of Arsenic as Crystalline Scorodite”, Impurity Control and Disposal in Hydrometallurgical Processes : International Symposium : 24th Annual Hydrometallurgical Meeting, Quebec, Canada, 1994, pp. 57-69, The British Library.

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