Method of making aluminum alkyls

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07F 506

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043648720

ABSTRACT:
A method of making trimethylaluminum wherein an aluminum trialkyl having at least two carbon atoms in the alkyl group is reacted with a methyl halide in the presence of a bismuth catalyst to form trimethylaluminum and an alkyl halide. A hydrocarbon solvent provides increased reaction rates.

REFERENCES:
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patent: 2744127 (1956-05-01), Liegler et al.
patent: 2839556 (1958-06-01), Liegler et al.
patent: 2863894 (1958-12-01), Smith
patent: 2931820 (1960-04-01), Barclay et al.
patent: 4118409 (1978-10-01), Eidt et al.

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