Synthesis, spectroscopy, photophysics of multi-chromophoric...

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Reexamination Certificate

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C327S527000, C540S145000, C514S185000

Reexamination Certificate

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07445845

ABSTRACT:
Novel multichromophoric complexes comprising the formulain-line-formulae description="In-line Formulae" end="lead"?R1—RA-[MC]-([RM]z-[MC])m-RA—R2in-line-formulae description="In-line Formulae" end="tail"?are provided. Polymeric compositions and devices comprising the same are also discussed. The complexes are characterized by a central bridging moiety comprising one or a plurality of linked conjugated macrocyclic molecules [MC] coupled to at least one inorganic moiety (R1and/or R2) through organic linker RA. Preparation methods include metal-mediated cross-coupling techniques. The complexes can be useful in nonlinear optical devices and other optoelectronic applications.

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