Solid acid catalyst containing tin and method for...

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Sulfur or compound containing same

Reexamination Certificate

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C423S594900, C423S618000

Reexamination Certificate

active

07442668

ABSTRACT:
An object is to provide a sulfated tin oxide catalyst with strong catalytic activity, and a method for preparation thereof. It was discovered that in the preparation of a solid acid catalyst containing tin, stronger solid acid properties than before could be achieved by preparing a support comprising a crystalline tin oxide, preferably metastannic acid, bringing this support into contact with organic acid ions, then bringing it into contact with a sulfate group-containing compound, and then calcining it. The solid acid catalyst of the present invention has a tin content of 30% or more by weight as metal in the catalyst, a sulfate group supported thereon and an argon adsorption heat of more than 30 kJ/mol, and is used in acid-catalytic reactions.

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