Soluble polyfunctional vinyl aromatic polymer and method of...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

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C526S135000, C526S146000, C526S147000, C526S209000, C526S216000, C526S217000, C526S221000, C526S222000, C526S237000, C526S284000, C526S347000

Reexamination Certificate

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10586969

ABSTRACT:
The present invention relates to a soluble polyfunctional vinylaromatic copolymer improved in heat resistance, resistance to thermal decomposition, solvent solubility, and processability. The soluble polyfunctional vinylaromatic polymer is obtained by cationically polymerizing, at a temperature of 20 to 120° C., one or more monomer ingredients including 20 to 100 mol % divinylaromatic compound (a) in the presence of a donor ingredient, e.g., a quaternary ammonium salt, with the aid of a Lewis acid catalyst and an initiator represented by the following general formula (1)wherein R1represents hydrogen or a monovalent C1-6hydrocarbon group; R2represents an aromatic or aliphatic hydrocarbon group having a valence of p; Z represents halogen or C1-6alkoxy or acyloxy; and p is an integer of 1 to 6; provided that when two or more R1's and Z's are present per molecule, they may be identical to different from each other.

REFERENCES:
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Nitadori, Y., et al.; “Synthesis of Soluble Poly (divinylbenzene) by Lithium Amide Catalyzed Anionic Polymerization;”Makromol Chem; vol. 179, pp. 2069-2073. (1978).
Nagasaki, Y., et al.; “Synthesis of soluble poly (divinylbenzene-co-styrene) and poly (divinylbenzene-co-vinylpyridine) by lithium amide-initiated anionic copolymerization;”Makromol Chem; vol. 189, pp. 723-731. (1988).
Hasegawa, H., et al.;“Synthesis of Linear Poly(divinylbenzene) through Proton-Transfer Polyaddition by Oxo Acids;”Macromolecules; vol. 13, pp. 1350-1354. (1980).
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