Promoters for controlling acidity and pore size of zeolite...

Chemistry of hydrocarbon compounds – Aromatic compound synthesis

Reexamination Certificate

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C585S446000, C585S467000

Reexamination Certificate

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10967881

ABSTRACT:
A metal-modified alkylation catalyst including a metalizeolite is provided where the metal is one or two selected from the group consisting of yttrium and a rare earth of the lanthanide series other than cerium. Where two metals are used, one may be Ce or La. The metal-promoted zeolite is useful as a molecular sieve aromatic alkylation catalyst for the production of ethylbenzene by the ethylation of benzene in the liquid phase or critical phase. An alkylation product is produced containing ethylbenzene as a primary product with the attendant production of heavier alkylated by-products of no more than 10-60 wt % of the ethylbenzene.

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patent: 6576796 (2003-06-01), Funke et al.
patent: 2003/0108467 (2003-06-01), Tran et al.
patent: 2004/0097770 (2004-05-01), Dakka et al.
patent: 2004/0162454 (2004-08-01), Gao et al.
patent: 0 507 761 (1992-10-01), None

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