Process for producing acetals

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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544352, 544357, 544367, 544369, 544430, 560 56, 560 57, 560 63, 560 64, 560 65, 560 81, 560100, 560102, 560116, 560118, 560180, 560182, 560183, 560184, 560186, 560187, 562467, 562473, 562474, 562475, 562498, 562508, 562579, 562580, 562586, 562587, 568561, 568542, 568544, 568715, 568807, 568808, 568809, 568811, 568816, 568822, 568841, 568852, C07C32100, C07C 3118, C07C 6334, C07C 6976

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057928762

ABSTRACT:
A process is described for producing acetals comprising reacting an aldehyde or a ketone with an alcohol in the presence of a titanium compound having an acetylacetone as a ligand, or in the presence of a compound selected from the group consisting of stannous chloride dihydrate, cerium chloride hexahydrate and bismuth chloride. The process can be used in the synthesis of unstable acetals or when water exists in the reaction mixture, and therefore the process can be used for a wide variety of applications.

REFERENCES:
Chemical Abstracts, vol. 99, No. 7, pp. 503-504, Aug. 15, 1983, AN 53125 & JP-58-55440, Apr. 1, 1983.
Chemical Abstracts, vol. 90, No. 17, pp. 462-463, Apr. 23, 1979, AN 137263, JP-53-132514, Nov. 18, 1978.
Journal of the Chemistry Society, Chemical Communications, No. 22, pp. 976-977, Nov. 15, 1978, Jean-Louis Luche, et al., "Efficient Synthesis of Acetals Catalysed by Rare Earth Chlorides".

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