Process for the synthesis of imidazoles

Drug – bio-affecting and body treating compositions – Designated organic active ingredient containing – Having -c- – wherein x is chalcogen – bonded directly to...

Reexamination Certificate

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C548S335100, C514S396000

Reexamination Certificate

active

10706474

ABSTRACT:
The present invention provides a process for the preparation of imidazoles by reacting a cyano compound with a silylalkylisocyanide compound. Such imidazoles are useful pharmacologically-active compounds and/or intermediates for the preparation of pharmacologically-active compounds.

REFERENCES:
patent: 5578616 (1996-11-01), Asianian et al.
patent: 5658903 (1997-08-01), Adams et al.
patent: 6008240 (1999-12-01), Phillips et al.
patent: 6235740 (2001-05-01), Barrish et al.
patent: 6329369 (2001-12-01), Chow et al.
patent: 0591027 (1994-04-01), None
patent: WO 9626927 (1995-01-01), None
patent: WO9629315 (1996-09-01), None
patent: WO 9823224 (1996-11-01), None
patent: WO 9924421 (1998-11-01), None
patent: WO9928315 (1998-11-01), None
patent: WO200023438 (1999-10-01), None
patent: WO0109128 (2000-07-01), None
patent: WO-2003/099795 (2003-05-01), None
Nispen et al, “Use of dilithio-tosylmethyl isocyanide in the synthesis of oxazoles and imidazoles”, Tetrahedron Letters, vol. 21, 1980, pp. 3723-3726.
Ranganathan et al, “Convenient synthesis of 2-thionaphthylmethyl isocyanide: a useful reagent for methyl isocyandie transfer”, vol. 29, No. 12, 1988, pp. 1435-1436.
Sisko et al, “An Investigation of Imidazole and Oxazole Synthesis Using Aryl-Substituted TosMIC Reagents”, J. Org. Chem. 2000, 65, 1515-24.
ten Have et al, “Novel Synthesis of 4(5)-Monosubstituted Imdiazoles vis Cycloaddition of Tosylmethyl Isocyanide to Aldimines”, Tetrahedron, 1997, vol. 53, No. 33, 11355-11368.
van Leusen et al, “Base-Induced Cycloaddition of Sulfonylmethyl Isocyanides to C, N Double Bonds. Synthesis of 1,5-Disubstituted and 1,4,5-Trisubstituted Imidazoles from Aldimines and Imidoyl Chlorides”, J. Org. Chem. 1977, 42, 1153.
Horne et al, “A Two-Step Synthesis of Imidazoles From Aldehydes Via 4-Tosyloxazolines”, Heterocycles, 1994, vol. 39, No. 1, 139-153.
S. Marcaccini, “The Use of Isocyanides in Heterocyclic Synthesis. A Review”, Organic Preparations and Procedures Int. 1993, 25 (2), 141-208.
N. Shih, “Novel Synthesis of N-Unsubstituted Imidazoles Using N-Trimethylsilylimines”, Tetrahydron Letters, 1993, vol. 34, No. 4, 595-598.
Mor et al, “Synthesis and biological assays of new H3-antagonists with imidazole and imidazole polar groups”, II Farmaco, 55, 2000,27-24.

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