Converting oxygenates to olefins over a catalyst comprising...

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – From nonhydrocarbon feed

Reexamination Certificate

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C585S640000

Reexamination Certificate

active

10227907

ABSTRACT:
The present invention provides a process for making an olefin product from an oxygenate-containing feedstock comprising:a) contacting the feedstock in a reaction zone with catalyst particles comprising a molecular sieve containing acid sites and having an average coke loading of 1 to 10 carbon atoms per acid site of said molecular sieve, under conditions effective to convert the feedstock into an olefin product stream and to provide unregenerated catalyst particles,b) removing a portion of said catalyst particles from said reaction zone and contacting said portion with a regeneration medium in a regeneration zone under conditions effective to obtain regenerated catalyst particles which have an average coke loading of no greater than 10 carbon atoms per acid site of said molecular sieve, andc) introducing said regenerated catalyst particles into said reaction zone to provide a catalyst mixture of unregenerated catalyst particles and regenerated catalyst particles, in an amount sufficient to provide an average coke loading on said catalyst mixture in an amount ranging from 1 to 10 carbon atoms per acid site of said molecular sieve.

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Bos et al. “Conversion of Methanol to Lower Olefins. Kinetic Modeling, Reactor Simulation, and Selection.”Ind. Eng. Chem. Res. vol. 34, pp. 3808-3816, (1995).
Soendararajan et al., “Modeling of Methanol to Olefins (MTO) Process in a Circulating Fluidized Bed Reactor,”Fuel, vol. 80, pp. 1187-1197 (2001).
“Conversion of Methanol to Lower Olefins. Kinetic Modeling, Reactor Stimulation, and Selection,” A.N. Rene Bos et al., Ind. Eng. Chem. Res., vol. 34, pp 3808-3816, 1995.
“Structural and chemical influences ont he MTO reaction: a comparison of chabazite and SAPO-34 as MTO catalysts,” Ivar M. Dahl et al., Microporous and Mesoporous Materials, vol. 29, pp. 185-190, 1999.
“The characteristics of SAPO-34, which influence the conversion of methanol to light olefins,” S. Wilson et al., Microporous and Mesoporous Materials, vol. 29, pp. 117-126, 1999.
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