Tire with low volatile alcohol emission rubber tread with...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

Reexamination Certificate

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Details

C525S332600, C525S333100, C525S333300, C525S342000, C525S343000, C525S232000, C525S236000, C524S495000, C524S492000, C524S493000

Reexamination Certificate

active

11212245

ABSTRACT:
The invention relates to a tire having a tread of a rubber composition with compositional limitations containing minimal, if any, of in situ formed volatile alcohol byproduct. The tread component rubber composition contains a combination or pre-hydrophobated silica reinforcement and siloxane functionalized styrene/butadiene copolymer elastomer. The pre-hydrophobated silica is prepared, prior to mixing with the elastomer(s), by reacting hydroxyl groups (e.g. silanol groups) contained on the surface of a precipitated silica with an alkoxyorganomercaptosilane or with a bis-3(triethoxysilylpropyl)polysulfide which contains an average of from 2 to 4 connecting sulfur atoms in its polysulfidic bridge to form a composite thereof which may optionally include an alkyl silane. The volatile alcohol byproduct (e.g. ethanol) therefrom is thereby removed from the pre-hydrophobated silica composite prior to its introduction into the rubber composition(s).

REFERENCES:
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patent: 6998448 (2006-02-01), Zanzig et al.
patent: 2002/0055568 (2002-05-01), Cruse et al.
patent: 2004/0054032 (2004-03-01), Zanzig et al.
patent: 1142730 (2001-10-01), None
patent: 1 400 559 (2004-03-01), None
patent: 1400559 (2004-03-01), None
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