Polar ordering of reactive chromophores in layer-by-layer...

Stock material or miscellaneous articles – Composite – Including interfacial reaction product of adjacent layers

Reexamination Certificate

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C428S411100, C428S500000, C385S122000

Reexamination Certificate

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11067218

ABSTRACT:
Thin films exhibiting second-order nonlinear optical (NLO) properties, as well as materials and methods for producing such films, are provided. The films are formed by depositing, on a substrate, alternate layers of a polyelectrolyte and a low molecular weight chromophore. The chromophore contains an electrophilic group that reacts with a previously deposited polyelectrolyte, and ionizable groups which present absorption sites for the next polyelectrolyte layer. The films find application in, for example, electro-optic modulators and frequency doubling devices.

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