Producing vinylidene fluoride substantially free from tetrafluor

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07C 2102

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active

039963012

ABSTRACT:
Tetrafluorocyclobutane is cracked to produce vinylidene fluoride and unavoidably minor amounts of tetrafluoroethylene and ethylene. The reaction effluent to which additional ethylene can be added is subjected to dimerization and/or codimerization conditions under which tetrafluoroethylene is converted to a product or products which can be removed from the desired vinylidene fluoride by conventional fractionation without danger of explosion. Separated tetrafluorocyclobutane can be recycled to the cracking operation. Octafluorocyclobutane can be cracked under optimum conditions in separate zone, usually more severe than those employed for tetrafluorocyclobutane.

REFERENCES:
patent: 2462345 (1949-02-01), Barrick
patent: 2733278 (1956-01-01), Anderson

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