Binaphthol derivatives and their use in optical resolution...

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof

Reexamination Certificate

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C568S425000, C568S631000, C568S635000, C568S841000, C564S074000, C564S078000, C564S184000, C564S218000, C564S223000

Reexamination Certificate

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11341707

ABSTRACT:
Disclosed herein are novel binaphthol derivatives and methods for the optical resolution of amino acids or amino alcohols and for the optical transformation of D, L-forms of amino acids using the same.

REFERENCES:
Kim et al., Enantioselective recognition of 1,2-amino alcohols by reversible formation of imines with resonance-assisted hydrogen bonds, Organic Letters, Jul. 2005, vol.7, No. 16, pp. 3525-3527.
Laura Favretto et al, “Highly Regioselective Microwave-Assisted Synthesis of Enantiopure C3-Symmetric Trialkanolamines,” Tetrahedron Letters 43 (2002), pp. 2581-2584.
Jik Chin et al, “Chiral Shift Reagent for Amino Acids Based on Resonance-Assisted Hydrogen Bonding,” Organic Letters (2004) vol. 6, No. 15, pp. 2591-2593.
Robert M. Williams et al., “Asymmetric Synthesis of Arylglycines,” Chemical Reviews, (1992), vol. 92, pp. 889-917.
Keiji Maruoka et al, “Enantioselective Amino Acid Synthesis by Chiral Phase-Transfer Catalysis,” Chemical Reviews, (2003), vol. 103, pp. 3013-3028.
Rudolf O. Duthaler, “Recent Developments in the Stereoselective Synthesis of α-Aminoacids”, (1994), vol. 50, No. 6, pp. 1539-1650.

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