Process for the preparation of partially hydrogenated derivative

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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C07C13100

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046224270

ABSTRACT:
Partially hydrogenated derivatives of 2-nitro-1,1,1-trifluoroalkanes, in particular 2-oximino- and 2-hydroxylamino-1,1,1-trifluoroalkanes, are prepared by catalytically hydrogenating 2-nitro-1,1,1-trifluoroalkanes until a maximum of 2.2 moles of hydrogen per mole of 2-nitro-1,1,1-trifluoroalkane have reacted.

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Journal of Catalysis, 82, pp. 56-65 (1983), Hydrogenation of Nitrocompounds with Supported Palladium Catalysts: Influence of Metal Dispersion and Nitrocompound Nature.

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