Supercritical fluid phase synthesis of methylene lactones...

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

Reexamination Certificate

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C549S326000

Reexamination Certificate

active

11169033

ABSTRACT:
Process for converting certain lactones to their alpha-methylene substituted forms that not only exhibits high initial activity (conversion), but also provides high reactor productivity (mass of product per mass of catalyst per unit of time) and sustained maintenance of a high level of activity and productivity with time on stream.

REFERENCES:
patent: 2003/0166949 (2003-09-01), Manzer et al.
patent: 2006/0025605 (2006-02-01), Hutchenson et al.
patent: 2006/0025607 (2006-02-01), Hutchenson et al.
patent: 2006/0025610 (2006-02-01), Hutchenson et al.
patent: 2006/0025611 (2006-02-01), Hutchenson et al.
patent: 2006/0025612 (2006-02-01), Hutchenson et al.
patent: 10298172 (1998-11-01), None
patent: WO 03/057683 (2003-07-01), None
Machine translation of JP 10298172, paragraph 27-33, May 12, 2006.
K. W. Hutchenson, “Organic Chemical Reactions and Catalysis in Supercritical Fluid Media” Supercritical Fluid Technology in Materials Science and Engineering, Y. P. Sun (Ed), Marcel Dekker, New York (2002) p. 87-187.
Kirk-Othmer Encyclopedia of Chem. Technology, 4th Ed., vol. 23, p. 452-477.
E. P. Barret, L. G. Joyner and P. P. Halenda, J. Amer. Chem. Soc., 73, 373 (1951).

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