Preparation of ethynylbenzenes

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260668D, C07C 1509

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041209095

ABSTRACT:
Ethynylbenzenes are prepared by the vapor phase catalytic dehydration of methyl phenyl ketones. The dehydration process is carried out at temperatures of from about 500.degree. to about 650.degree. C. using an alumina-containing catalyst. An example of the process is the dehydration of acetophenone to form phenylacetylene.

REFERENCES:
patent: 1098859 (1914-06-01), Webel
patent: 1977178 (1934-10-01), Dohse et al.
patent: 2443732 (1948-06-01), Ipatieff

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