Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Metal – metal oxide or metal hydroxide
Patent
1983-07-27
1985-04-23
Shine, W. J.
Catalyst, solid sorbent, or support therefor: product or process
Catalyst or precursor therefor
Metal, metal oxide or metal hydroxide
502330, 502332, 502333, 502334, 4232135, B01J 2104, B01J 2310, B01J 2358
Patent
active
045131015
ABSTRACT:
Alumina particle catalysts which can be used for auto emission control and especially as a three-way catalyst have increased performance. The alumina particles which are preferably spheroids have a low compacted bulk density of about 20 to 36 pounds per cubic foot and a smaller size on the order of less than 2.6 mm for the preferred spheroids. The spheroid embodiment also has a high crush strength. Because of the small size the ratio of the geometric surface area to the bulk volume (GSA/BV) is at least about 14 cm.sup.2 /cm.sup.3. These alumina particles are impregnated with a catalytically-effective amount of one or more platinum group metals such as platinum, palladium or rhodium and additional promoters can also be added. In the preferred embodiment the alumina particles have a GSA/BV ratio of from about 17 to 25 cm.sup.2 /cm.sup.3 for substantially improved performance.
REFERENCES:
patent: 4390456 (1983-06-01), Sanchez et al.
patent: 4392987 (1983-07-01), Laine et al.
Ernest et al, "Development of More Active and Durable Automotive Exhaust Catalysts", Society of Automotive Engineers, Paper No. 800083, Feb. 1980.
Ernest Michael V.
Kim Gwan
Peters Alan W.
Cabic Edward J.
Shine W. J.
W. R. Grace & Co.
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