Mesoporous mixed oxide materials as a new class of SO 2...

Chemistry of inorganic compounds – Oxygen or compound thereof – Metal containing

Reexamination Certificate

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C423S594100, C423S594300, C423S595000, C423S599000, C423S594120, C423S594140, C423S263000, C423S594500, C423S021100, C423S055000, C423S050000, C423S140000, C423S042000, C423S101000, C423S071000, C423S085000, C502S303000, C502S304000, C502S305000, C502S324000, C502S325000, C502S345000, C502S349000, C502S343000

Reexamination Certificate

active

07132093

ABSTRACT:
The oxide materials are of the class of ternary mesoporous mixed oxide materials including lanthanum, a metal M selected from the group consisting of Cr, Mn, Fe, Co, Ni, Cu and Zn, and zirconium or cerium such a mesoporous La—Co—Zr mixed oxide material designated as Meso LCZ[x] where x is the atomic ratio (La+Co)/La+Co+Zr. They are useful as catalysts since they show high activities for hydrocarbon oxidation and good resistance against poisoning agents. These highly ordered mesoporous mixed oxides are synthesized by: preparing an amorphous solution of a La-M precursor and adding a salt of zirconium or cerium thereto; acidifying the amorphous solution in the presence of a surfactant under conditions to obtain a clear homogeneous solution; adjusting pH of the solution under conditions to form a solid precipitate; separating the solution and surfactant from the precipitate; and calcinating the precipitate.

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