Apparatus for producing high molecular weight liquid...

Chemical apparatus and process disinfecting – deodorizing – preser – Chemical reactor – Waste gas purifier

Reexamination Certificate

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C422S198000, C422S211000, C422S213000

Reexamination Certificate

active

07001574

ABSTRACT:
A mixture of natural gas and air is converted to a C5–C19diesel fuel-grade liquid hydrocarbon. The natural gas and air mixture is supplied to the input of a catalytic partial oxidation reactor. The carbon-containing gas output of the catalytic partial oxidation reactor is connected as an input to a first Fischer-Tropsch reactor, to thereby form a first diesel fuel grade C5–C19liquid hydrocarbon output. A carbon-containing gas output of the first Fischer-Tropsch reactor is connected to the input of a second Fischer-Tropsch reactor, to thereby form a second diesel fuel grade C5–C19liquid hydrocarbon output. The catalytic partial oxidation reactor contains a platinum group catalyst, a promoted platinum group catalyst, a rhodium catalyst, or a platinum promoted rhodium catalyst. Each of the Fischer-Tropsch reactors contain a catalyst that is made up of from about 3 to about 60 parts-by-weight cobalt and from about 0.1 to about 100 parts-by-weight of at least one metal selected from a group consisting of cerium, lanthanum and ruthenium per 100 parts-by-weight of a support selected from a group consisting of silica, alumina and combinations of silica and alumina, and more preferably a catalyst that is made up of about 20 percent by weight cobalt, about 0.1 percent by weight ruthenium, about 0.1 percent by weight platinum, the remainder being an alumina support.

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