Germanium bridged metallocenes producing polymers with increased

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526160, 526352, 526943, 502103, 502117, 502152, 556 28, 556 53, 556 43, 556 46, 556 58, 556136, 556138, 987 2, C08F 4642, C07F 1700

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060341920

ABSTRACT:
This invention relates to a process for polymerizing ethylene comprising contacting ethylene and optional comonomers with a catalyst system comprising an activator and a transition metal compound represented by the formula: ##STR1## Wherein R.sub.1 and R2 are independently hydrogen or a group having up to 100 carbon atoms, Cp.sub.1 is a bulky ligand; Cp.sub.2 is a bulky ligand or a heteroatom optionally bound to a C.sub.1 to C.sub.50 hydrocarbyl group, n is the valence state of the transition metal, Tm is a Group 3 to 10 metal, and each X is independently an anionic leaving group.

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