Catalytic mixtures for ammoxidation of paraffins

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Boron or compound containing same

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502206, 502207, 502209, 502215, 502247, 502248, 502249, 502255, 502304, 502306, 502307, 502308, 502309, 502311, 502312, 502321, 502322, 502353, 502354, B01J 2310, B01J 2328, B01J 2318, B01J 2102

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047881739

ABSTRACT:
Ammoxidation of C.sub.3 to C.sub.5 acyclic alkanes with NH.sub.3 and O.sub.2 using (1) a mole ratio of alkane:NH.sub.3 in the range from 2 to 16 and a mole ratio of alkane:O.sub.2 in the range 1 to 10 and (2) a mixture of particulate catalyst compositions, the first being especially effective to promote formation of an unsaturated nitrile and an olefin from the paraffin, and the second catalyst composition being especially effective to promote the conversion of the olefin to the unsaturated nitrile. Catalytic compositions useful in the process are disclosed.

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