Olefin polymerization catalyst system

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

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C526S171000, C526S172000, C526S348000, C502S155000, C502S167000

Reexamination Certificate

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07094848

ABSTRACT:
This invention relates to a compound represented by the formula:wherein M is selected from groups 3–11 of the periodic table;L1represents a formal anionic ligand, L2represents a formal neutral ligand, a is an integer greater than or equal to 1; b is greater than or equal to 0; c is greater than or equal to 1, E is nitrogen or phosphorus, Ar0is arene, R1–R4are, each independently, selected from hydrogen, hydrocarbyl, substituted hydrocarbyl or functional group, provided however that R3and R4do not form a naphthyl ring, N is nitrogen and O is oxygen.This invention further relates to a process to oligomerize and/or polymerize unsaturated monomers using the above compositions, optionally combined with an activator.

REFERENCES:
patent: 3180831 (1965-04-01), Odell et al.
patent: 6037297 (2000-03-01), Stibrany et al.
patent: 6143857 (2000-11-01), Bansleben et al.
patent: 6147173 (2000-11-01), Holtcamp
patent: 6147174 (2000-11-01), Holtcamp et al.
patent: 6180788 (2001-01-01), Stibrany
patent: 6197714 (2001-03-01), Bansleben et al.
patent: 6197715 (2001-03-01), Bansleben et al.
patent: 6211105 (2001-04-01), Holtcamp
patent: 6258903 (2001-07-01), Mawson et al.
patent: 6265505 (2001-07-01), McConville et al.
patent: 6265513 (2001-07-01), Murray et al.
patent: 6268447 (2001-07-01), Murray et al.
patent: 6281306 (2001-08-01), Oskam et al.
patent: 6320002 (2001-11-01), Murray et al.
patent: 6333389 (2001-12-01), Whiteker et al.
patent: 6340730 (2002-01-01), Murray et al.
patent: 6346584 (2002-02-01), Wenzel et al.
patent: 6372868 (2002-04-01), Szul et al.
patent: 6380328 (2002-04-01), McConville et al.
patent: 6399722 (2002-06-01), Szul et al.
patent: 6410664 (2002-06-01), Bansleben et al.
patent: 6417303 (2002-07-01), Stibrany et al.
patent: 6506704 (2003-01-01), Bansleben et al.
patent: 6562922 (2003-05-01), Bansleben et al.
patent: 6897275 (2005-05-01), Wang et al.
patent: 2004/0171479 (2004-09-01), Bazan et al.
patent: 99556 (1973-08-01), None
patent: 1 217 013 (1996-05-01), None
patent: 0 990 664 (1999-04-01), None
patent: 0 990 664 (2000-04-01), None
patent: 1 217 013 (2002-06-01), None
patent: 96/23010 (1996-08-01), None
patent: 98/30609 (1998-07-01), None
patent: 98/42664 (1998-10-01), None
patent: 98/42665 (1998-10-01), None
patent: 99/30822 (1999-06-01), None
patent: 00/04058 (2000-01-01), None
patent: 00/15676 (2000-03-01), None
patent: 00/29454 (2000-05-01), None
patent: 00/35969 (2000-06-01), None
patent: 00/37509 (2000-06-01), None
patent: 00/37511 (2000-06-01), None
patent: 00/37512 (2000-06-01), None
patent: 00/56781 (2000-09-01), None
patent: 00/56785 (2000-09-01), None
patent: 00/56786 (2000-09-01), None
patent: 00/56787 (2000-09-01), None
patent: 01/30860 (2001-05-01), None
patent: 01/30861 (2001-05-01), None
patent: 01/30862 (2001-05-01), None
patent: 01/40325 (2001-06-01), None
patent: 01/40330 (2001-06-01), None
patent: 01/44321 (2001-06-01), None
patent: 02/06358 (2002-01-01), None
patent: 02/10227 (2002-02-01), None
patent: 02/18452 (2002-03-01), None
patent: 02/32968 (2002-04-01), None
patent: 02/38629 (2002-05-01), None
patent: 02/45854 (2002-06-01), None
patent: 02/46243 (2002-06-01), None
patent: 02/46250 (2002-06-01), None
patent: 02/51884 (2002-07-01), None
Younkin, T.R.; Connor, E.F.; Henderson, J.I.; Friederich, S.K.; Grubbs, R.H.; Bansleben, D.A.; “Neutral, Single-Component Nickel (II) Polyolefin Catalysts That Tolerate Heteroatoms”,Science2000, 287, 460-462.
Wang, C. Friederich, S.; Younkin, T.R.; Grubbs, R.H.; Bansleben, D.A.; Day, M.W.; “Neutral Nickel (II)-Based Catalysts for Ethylene Polymerization”,Organometallics1998, 17, 3149-3151.
Hicks, F.; Brookhart, M.; “A Highly Active Anilinotropone-Based Neutral Nickel (II) Catalyst for Ethylene Polymerization”,Organometallics2001, 20, 3217-3219.
Connor, E.F.; Younkin, T.R.; Henderson, J.I.; Hwang, S.; Grubbs, R.H.; Roberts, W.P.; Litzau, J.J., “Linear Functionalized Polyethylene Prepared with Highly Active Neutral Ni (II) Complexes”,J. Pol. Sci. A. 2002, 40, 2842-2854.
Schroeder, D.L.; Keim, w.; Zuideveld, M.A.; Mecking, S, “Ethylene Polymerization by Novel, Easily Accesible Catalysts Based on Nickel (II) Diazene Complexes”,Macromolecules, 2002, 35, 6071-6073.
Laali, K.; Szele, I.; Zollinger, H., “Dediazoniation of Arendediazonium Ion. Part XXII, Reactions of 2,6-Dialkyl-Substituted Benzenediazonium Ions in Super Acids, Acetonitrile and Acetone”Helvetica Chimica Acta1983, 66, 1737-1747.
Petrillo, G.; Novi, M.; Garbarino, G.; Filiberti, M., The Reaction Between Arendiazonium Tetrafloroborates and Alkaline Thiocarboxylates in DMSO: A Convenient Access to Aryl Thiolesters and other Aromatic Sulfur Derivatives:Tetrahedron1989, 45, 7411-7420.
Drent et al., “Palladium Catalysed Copolymerisation of Ethene with Alkylacrylates: Polar Comonomer Built into the Linear Polymer Chain”, Chem. Commun. 2002, 744-745.
Stribrany et al., “Cu Catalysts for Homo- and Copolymerization of Olefins and Acrylates”, Polymeric Materials: Science & Engineering 2002, 86, 325.
Stibrany et al., “Cu Catalysts for Homo- and Copolymerization of Olefins and Acrylates”, Beyond Metallocenes: Next-Generation Polymerization Catalysts, ACS Symposium Series 857, Washington, DC. 2003, 222-230.
Wang et al., “Novel Nickel Catalysts for Ethylene/Polar Monomer Copolymerization”, Polymeric Materials: Science & Engineering 2002, 86, 322.
Johnson et al., “Copolymerization of Ethylene and Propylene with Functionalized Vinyl Monomers by Palladium(II) Catalysts”, J. Am. Chem. Soc. 1996, 118, 267-268.
Mecking et al., “Mechanistic Studies of the Palladium-Catalyzed Copolymerization of Ethylene and α-Olefins with Methyl Acrylate”, J. Am. Chem. Soc. 1998, 120, 888-899.
Johnson et al., “Copolymerization of Ethylene and Acrylates by Nicket Catalysts”, Polymeric Materials: Science & Engineering 2002, 86, 319.
Liu et al., “Ethylene Polymerization and Ethylene/Methyl 10-Undecenoate Copolymerization Using Nickel(II) and Palladium(II) Complexes Derived from a Bulky P,O Chelating Ligand”, Organometallics 2002, 21, 2836-2838.
Ittel et al., “Late-Metal Catalysts for Ethylene Homo- and Copolymerization”, Chem. Rev. 2000, 100, 1169-1203.
Gibson et al., “Advances in Non-Metallocene Olefin Polymerization Catalysts”, Chem. Rev. 2003, 103, 283-315.
Stibrany et al., “Polymerization and Copolymerization of Olefins and Acrylates by Bis(benzimidazole) Copper Catalysts”, Macromolecules 2003, 36, 8584-8586.
Grubbs et al., “Neutral Single-Component Nickel (II) Polyolefin Catalysts That Tolerate Heteroatoms”, Science, vol. 287, (Jan. 27, 2000), pp. 460-462.
Wang Et al., “Neutral Nickel(II)-Based Catalysts for Ethylene Polymerization”, Organometallics, 1998, 17, pp. 3149-3151.

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