Process for producing thermosetting finishing powders

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260 4228, 260 4244, 260 7841, 260 793R, 260835, 260836, 260837R, 427 27, 428220, 428463, 526 16, 526 49, 526 56, 526 78, 526 86, 526271, 526317, 526318, 526320, 526321, 528502, 528503, C08F 220, C08F 600, C08L 3304

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040426459

ABSTRACT:
Solid copolymers are produced by copolymerizing a mixture of: (A) at least 30% by weight of a monomer having the formula: ##STR1## wherein R.sub.1 is H or CH.sub.3 and R.sub.2 is an alkyl radical containing from 1 to 14 carbon atoms; (B) from 3 to 20% by weight of an ethylenic .alpha., .beta. unsaturated carboxylic acid or anhydride thereof, or from 3 to 40% by weight of glycidyl acrylate or glycidyl methacrylate; and (C) from 0 to 67% by weight of a monomer copolymerizable with said monomers (A) and (B). Preferably, the mixture is first bulk-polymerized until conversion to the copolymer is from 10 to 80% by weight and the polymerization is completed by suspension-polymerization. Thermosetting solid coating compositions are produced by mixing a major proportion of a solid copolymer so produced with a minor proportion of a cross-linking compound or with an epoxy resin containing at least 2 epoxy radicals in the molecule in presence of a tertiary amine curing accelerator.

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