Metal complex-based electron-transfer mediators in...

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

Reexamination Certificate

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C556S136000, C556S141000, C429S111000, C359S265000, C252S586000

Reexamination Certificate

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07019138

ABSTRACT:
This present invention provides a metal-ligand complex and methods for using and preparing the same. In particular, the metal-ligand complex of the present invention is of the formula:in-line-formulae description="In-line Formulae" end="lead"?La-M-Xbin-line-formulae description="In-line Formulae" end="tail"?where L, M, X, a, and b are those define herein. The metal-ligand complexes of the present invention are useful in a variety of applications including as electron-transfer mediators in dye-sensitized solar cells and related photoelectrochromic devices.

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patent: 6734305 (2004-05-01), Pierre et al.
Chen, Y. D. et al., Journal of the Electrochemical Society, Jan. 1982, vol. 129, No. 1, pp. 61-66.
Rao et al., Inorganica Chimica Acta, vol. 41, pp. 221-226 (1980).
C. Wen et al., “Effects of Silver Particles on the Photovoltaic Properties of Dye-Sensitized TiO2Thin Films,” Solar Energy Materials & Solar Cells, vol. 61, (2000) pp. 339-351.
Pierre Bonhote et al., “Redox Mediators for Electrochemical Photovoltaic Cells Based on Dye-Sensitized TiO2Electrodes,” presented at the 10thInternational Conference on Photochemical Conversion and Storage of Solar Energy (IPS-10), Interlaken, Switzerland, (1994) Abstract C2.
Shawn A. Sapp et al., “Substituted Polypridine Comlplexes of Cobalt(II/III) as Efficient Electron-Transfer Mediators in Dye-Sensitized Solar Cells,” J. Am. Chem. Soc. (2002), vol. 124, No. 37, pp. 11215-11222.

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