Method and composition to decrease iron sulfide deposits in...

Fluid handling – Processes – Affecting flow by the addition of material or energy

Reexamination Certificate

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C210S235000, C210S236000, C210S634000, C210S638000, C210S709000, C210S712000, C210S724000, C210S748080, C210S912000, C423S150100, C585S818000

Reexamination Certificate

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06986358

ABSTRACT:
The levels of iron sulfide present in a conduit, such as a pipeline, are reduced by contacting the conduit, on an inner surface, with a composition obtained from an aqueous solution containing at least one compound of Formula (I)and at least one amine or corresponding ammonium derivative in the presence of a solvent, wherein X is an anion of valency n. Preferably, the pH of the solution is about 8. Alternatively, the method employs a composition comprising tris(hydroxymethyl)phosphine (TRIS) and at least one amine or corresponding ammonium derivative. The amine preferably is ammonia or a primary alkylamine. The compositions readily complex and thereby dissolve deposits of iron(II) sulfide, removing them from the conduit.

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Jeffery, et al., “Self assembly of a novel water soluble iron(II) macrocyclic phosphine complex from tetrakis(hydroxymethyl)phosphonium sulfate and iron (II) ammonium sulfate: single crystal X-ray structure of the complex [Fe(H2O)2{RP(CH2N(CH2PR2)CH2)2PR}]SO44H2O (R=CH2OH)”,Chem. Commun., 101-102 (2000), The Royal Society of Chemistry, Great Britain.
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