Converting natural gas to longer-chain hydrocarbons

Chemistry: fischer-tropsch processes; or purification or recover – Liquid phase fischer-tropsch reaction

Reexamination Certificate

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C518S702000, C518S704000, C518S712000

Reexamination Certificate

active

07109248

ABSTRACT:
Natural gas is processed to generate longer-chain hydrocarbons, the process comprising subjecting the gas to steam reforming to generate a mixture of carbon monoxide and hydrogen, and then subjecting this mixture to Fischer-Tropsch synthesis. The Fischer-Tropsch synthesis is performed at an elevated temperature above 230° C. and with a gas hourly space velocity greater than 10 000 hr−1so as to achieve a selectivity to the production of C5+ hydrocarbons that is less than 65%. The resulting liquid product can be used as a vehicle fuel, while the tail gases may be used to generate electricity.

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Yuan-Yuan Ji et al, “Effect of reaction conditions on the product distribution during Fischer-Tropsch synthesis over an industrial Fe-Mn catalyst,” Applied Catalysis A: General, 214 (2001), pp. 77-86.

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