Resins curable with actinic energy ray, process for the...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From heterocyclic reactant containing as ring atoms oxygen,...

Reexamination Certificate

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C528S406000, C526S319000, C428S500000

Reexamination Certificate

active

06861500

ABSTRACT:
A photocurable and thermosetting resin composition comprises (A) an actinic energy ray-curable resin having at least one structure represented by the following general formula (1), (B) a polymerization initiator, (C) a diluent, and (D) a polyfunctional oxetane compound. The actinic energy ray-curable resin mentioned above can be produced by causing the reaction of (a) a polyfunctional oxetane compound with (b) an unsaturated monocarboxylic acid and the subsequent reaction of (c) a polybasic acid anhydride with a primary hydroxyl group of the resultant modified oxetane resin (a′).wherein R1represents a hydrogen atom or an alkyl group of 1 to 6 carbon atoms, R2, R3and R4independently represent a hydrogen atom, an alkyl group of 1 to 6 carbon atoms, an aryl group, an aralkyl group, a cyano group, a fluorine atom, or a furyl group, and X represents a polybasic acid anhydride residue.

REFERENCES:
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Tadtomi Nishikubo & Nazuya Sato, New Addition Reactions of Cyclic Ethers with Esters and Thioesters Catalyzed by Quatemary Ammonium Salts or Crown Ether Complexes. Chemistry Letters, pp. 697-700, 1991.
Tadatomi Nishikubo, Astsushi Kameyama, Akira Suski, A Novel synthesis of polyesters with pendant hydroxyl groups by polyaddition of bis (oxtenane) with dicarboxylic acids catalyzed by quatemary onium salts. Reactive & Functional Polymers 37 (1998) 19-25.
Tadatomi Nishikubo, Astsushi Kameyama, Muneharu Ito, Tomoe Nakajima, Haruo Miyazaki, A Novel Synthesis of Polyethers with Pendant Hydroxyl Groups by Polyaddition of Bis (Oxetane)s with Bis (phenol)s Journal of Polymer Science: Part A : Polymer Chemistry, vol. 37, 2781-2790 (1999).

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