Process for the preparation of bisphenols with zeolites

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

Reexamination Certificate

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C568S723000, C568S727000, C502S027000, C502S029000, C502S033000

Reexamination Certificate

active

06872859

ABSTRACT:
The present invention relates to a process for preparing bisphenols which comprises reacting a carbonyl compound containing at least two carbon atoms with an aromatic compound, containing a hydroxyl group and at least one hydrogen atom bound to the aromatic ring, in the presence of a catalyst comprising a zeolite characterized by a spaciousness index equal to or higher than 8. The invention also relates to a method for the regeneration of the zeolitic catalyst used in this process and comprises subjecting the exhausted catalyst to hot treatment with a suitable aromatic compound containing at least one activating group, preferably the same hydroxylated aromatic compound used in the process for the preparation of bisphenols from which the exhausted catalyst derives.

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K. Nowinska et al.: “Synthesis of bisphenol-A over heteropoly compounds encapsulated into mesoporous molecular sieves” Applied Catalysis A: General, vol. 203, No. 1, pp. 91-100, Sep. 18, 2000.
D. Das et al.: “Sulfonic acid functionalized mesoporous MCM-41 silica as a convenient catalyst for Bisphenol-A synthesis” Chem. Commun., vol. 21, p. 2179 Oct. 5, 2001.

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