Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Electrode
Reexamination Certificate
2005-05-10
2005-05-10
Chaney, Carol (Department: 1745)
Chemistry: electrical current producing apparatus, product, and
Current producing cell, elements, subcombinations and...
Electrode
C429S218100, C429S231950
Reexamination Certificate
active
06890686
ABSTRACT:
The invention provides novel lithium-containing phosphate materials having a high proportion of lithium per formula unit of the material. Upon electrochemical interaction, such material deintercalates lithium ions, and is capable of reversibly cycling lithium ions. The invention provides a rechargeable lithium battery which comprises an electrode formed from the novel lithium-containing phosphates.
REFERENCES:
patent: 3736184 (1973-05-01), Dey et al.
patent: 4009092 (1977-02-01), Taylor
patent: 4049891 (1977-09-01), Hong et al.
patent: 4098687 (1978-07-01), Yang
patent: 4166159 (1979-08-01), Pober
patent: 4194062 (1980-03-01), Carides et al.
patent: 4322485 (1982-03-01), Harrison et al.
patent: 4394280 (1983-07-01), von Alpen et al.
patent: 4464447 (1984-08-01), Lazzari et al.
patent: 4465744 (1984-08-01), Susman et al.
patent: 4477541 (1984-10-01), Fraioli
patent: 4512905 (1985-04-01), Clearfield et al.
patent: 4668595 (1987-05-01), Yoshino et al.
patent: 4707422 (1987-11-01), de Neufville et al.
patent: 4792504 (1988-12-01), Schwab et al.
patent: 4828834 (1989-05-01), Nagaura et al.
patent: 4830939 (1989-05-01), Lee et al.
patent: 4935317 (1990-06-01), Fauteux et al.
patent: 4985317 (1991-01-01), Adachi et al.
patent: 4990413 (1991-02-01), Lee et al.
patent: 5037712 (1991-08-01), Shackle et al.
patent: 5130211 (1992-07-01), Wilkinson et al.
patent: 5232794 (1993-08-01), Krumpelt et al.
patent: 5262253 (1993-11-01), Golovin
patent: 5300373 (1994-04-01), Shackle
patent: 5336572 (1994-08-01), Koksbang
patent: 5399447 (1995-03-01), Chaloner-Gill et al.
patent: 5411820 (1995-05-01), Chaloner-Gill
patent: 5418090 (1995-05-01), Koksbang et al.
patent: 5418091 (1995-05-01), Gozdz et al.
patent: 5425932 (1995-06-01), Tarascon
patent: 5435054 (1995-07-01), Tonder et al.
patent: 5456000 (1995-10-01), Gozdz et al.
patent: 5460904 (1995-10-01), Gozdz et al.
patent: 5463179 (1995-10-01), Chaloner-Gill et al.
patent: 5482795 (1996-01-01), Chaloner-Gill
patent: 5514490 (1996-05-01), Chen et al.
patent: 5540741 (1996-07-01), Gozdz et al.
patent: 5580430 (1996-12-01), Balagopal et al.
patent: 5643695 (1997-07-01), Barker et al.
patent: 5674645 (1997-10-01), Amatucci et al.
patent: 5702995 (1997-12-01), Fu
patent: 5721070 (1998-02-01), Shackle
patent: 5910382 (1999-06-01), Goodenough et al.
patent: 6004697 (1999-12-01), Thackeray et al.
patent: 6153333 (2000-11-01), Barker
patent: 0 680 106 (1995-11-01), None
patent: 0 680 106 (1995-11-01), None
patent: 1 049 182 (2000-11-01), None
patent: 1 093 172 (2001-04-01), None
patent: 61-263069 (1986-11-01), None
patent: 6-251764 (1994-09-01), None
patent: WO 98 12761 (1998-03-01), None
patent: WO 9812761 (1998-03-01), None
patent: WO 9930378 (1999-06-01), None
patent: WO 0001024 (2000-01-01), None
patent: WO 0057505 (2000-09-01), None
Nanjundaswamy et al., “Synthesis, redox potential evaluation and electrochemical characteristics of NASICON-related-3D framework compounds”, Solid State Ionics 92 (1996) 1-10.*
Cretin, et al. “Detection and selectivity properties of Li+ ion selective electrodes based on NASICON-types ceramics”, Analytica Chimica Acta 354 (1997) 291-299.*
A. B. Bykov et al., Superionic Conductors Li3M2(PO4)3 (M=Fe, Sc, Cr): Synthesis, Structure and Electrophysical Properties, Solid State Ionics 38 (1990) 31-52.
Rangan et al., New Titanium-Vanadium Phosphates of Nasicon and Langbeinite Structures, and Differences between the Two Structures Toward Deintercalation of Alkali Metal, Journal of Solid State Chemistry 109, 116-121 (1994).
Kirkby et al, Crystal Structure of Potassium Aluminum Fluoride Phosphate, KAIFPO4, Department of Chemistry, University of Toronto, Toronto, Ontario, Canada, M5S 1A1.
J. Arlt et al., Na5AIF2(PO4)2: Darstellung, Kristallstruktur und Ionenleitfahigkeit, Z. anorg. allg. Chem. 547 (1987) 179-187.
P G Nagornyi et al., Preparation and Structure of the New Flouride Phosphate Na5CrF2(PO4)2, Russian Journal of Inorganic Chemistry 35 (4) 1990.
Loiseau et al., NH4FePO4F: Structural Study and Magnetic Properties, Journal of Solid State Chemistry III, 390-396 (1994).
LeMeins et al., Phase Transitions in the Na3M2(PO4)2F3 Family (M=Al3+, V3+, Cr3+, Fe3+, Ga3+): Synthesis, Thermal, Structural, and Magnetic Studies, Journal of Solid State Chemistry 148, 260-277 (1999).
Yakubovich et al., Inorganic Compounds: The Mixed Anionic Framework in the Structure of Na2{MnF[PO4]}, Acta Cryst. (1997) C53, 395-397.
Moss et al., On the X-ray Identification of Amblygonite and Montebrasite, Mineralogical Magazine, Sep. 1969, vol. 37, No. 287.
LeMeins et al., Ionic Conductivity of Crystalline and Amorphous Na3AI2(PO4)2F3, Solid State Ionics III (1998) 67-75.
M. Dutreilh et al., Synthesis and Crystal Structure of a New Lithium Nickel Fluorophosphate Li2 [NiF(PO4)] With an Ordered Mixed Anionic Framework, Journal of Solid State Chemistry 142, 1-5 (1999).
Manthiram et al., Lithium Insertion Into Fe2(SO4)3 Frameworks, Journal of Power Sources, 26 (1989) 403-408.
Amblygonite Mineral Data; http://webmineral.com/data/Amblygonite.shtml.
Lacroixite Mineral Data, http://webmineral.com/data/Lacroixite.shtml.
Montebrasite Mineral Data, http://webmineral.com/data/Montebrasite.shtml.
Tavorite Mineral Data, http://webmineral.com/data/Tavorite.shtml.
A. Nadiri et al., Lithium Intercalation in Lithium Titanium Phosphate, C. R. Acad. Sci., Ser. 2 (1987), 304 (9), 415-18 (Abstract Provided).
Genkina et al., Phase Formation and Crystallochemistry of Iron Phosphates Formed Under Hydrothermal Conditions, Izv. Akad. Nauk SSSR, Neorg. Mater. (1988), 24 (7), 1158-62 (Abstract Only).
Genkina et al., Crystal Structure of Synthetic Tavorite (LiFe[PO4] (OH,F)), Kristallografiya (1984), 29 (1), 50-5 (Abstract Only).
International Search Report, PCT/US01/08132.
Mt. Averbuch-Pouchot et al., “Topics in Phosphate Chemistry”, World Scientific 1996.
J. Gopalakrishnan et al., V2(PO4)3: A Novel NASICON-Type Vanadium Phosphate Synthesized by Oxidative Deintercalation of Sodium from Na3V2(PO4)3, Chem. Mater., vol. 4, No. 4, 1992, p. 745-747.
International Search Report, PCT/US00/04401 (attached to WO 00/57505).
International Search Report for PCT/US97/15544; EPO—Jan. 13, 1998.
Delmas et al., “The Nasicon-type . . . Materials”; SSI (1988) 28-30 (419-423).
Hagenmuller et al., “Intercalation in 3-D . . . Features”; Mat. Res. Soc. Proc., SSI, (1991) 323-34.
Chem. Abstrs. Svs., (1997); XP 2048304.
Padhi et al., “Lithium Intercalation into Nasicon-type . . . and Li2FeTi(PO4)3” 37th Power Sources Conference; Cherry Hill, New Jersey; Conference Date: Jun. 17-20, 1996, published Oct. 15, 1996.
J. Gopalakrishnan and K. Kasthuri Rangan, “V2(PO4)3: A Novel NASICON-Type Vanadium Phosphate Synthesized by Oxidative Deintercalcalation of Sodium from Na3V2(PO4)3,” Chemistry of Materials, vol. 4, No., 4, 745-747, Jul./Aug. 1992.
K. Kasthuri Rangan and J. Gopalakrishnan, “New Titanium-Vanadium Phosphates of Nasicon and Langbeinite Structures, and Differences Between the Two Structures Toward Deintercalation of Alkali Metal,” Journal of Solid State Chemistry, 109, 116-121, 1994.
Delmas et al., “The Chemical Short Circuit Method . . . ”, Mat. Res. Bull., vol. 23, pp. 65-72 (month not available), 1988.
Ivanov-Schitz et al., “Electrical . . . electrodes”; SSI (Oct. 1996) 91 (93-99).
Cretin et al., “Study . . . Sensors”, JR. EP. Ceramic Soc., (1995) (vol. 15, No. 11) (1149-56).
Chem. Abstrs. Svs., (1995) XP 2048305.
Patents Abstracts of Japan (1994) vol. 18, No. 64 (Abstr. for JP 06251764).
Okada et al., “Fe2(SO4)3as a Cathode Material for Rechargeable Lithium Batteries”, status as publication to be verified; cited by Examiner in SN 08/717,979.
Adachi et al., “Lithium Ion Conductive Solid Electrolyte”, Chemical Abstracts 112 129692 (1981).
Delmas et al., “A Nasicon-Type Phase as Intercalation Electrode: Sodium Titanium Phosphate (NaTi2(PO4)3”, Mater. Res. Bull. (1987).
Nanjundaswamy et al., “Synthesis
Chaney Carol
Kovacevic Cynthia S.
Ross Michael D.
Valence Technology Inc.
Williams Roger A.
LandOfFree
Lithium-containing phosphate active materials does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Lithium-containing phosphate active materials, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Lithium-containing phosphate active materials will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-3417476