Method of preparing exfoliated nitropolymer/silicate...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

Reexamination Certificate

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C525S130000, C524S565000, C524S445000, C524S186000, C524S447000, C523S210000

Reexamination Certificate

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06881798

ABSTRACT:
Disclosed is a preparation method of an exfoliated nitropolymer/silicate nanocomposite by emulsion polymerization of monomers forming the polymer in an aqueous dispersion of non-modified, layered silicate in the presence of a reactive emulsifier having both a radical-polymerizable vinyl group and a functional group with affinity for silicate. In the process of the polymerization, silicate is fully exfoliated and uniformly dispersed in the polymer. Therefore, only a small amount of silicate is sufficient to improve thermal and mechanical properties of the polymer. Further, the method is advantageous in terms of a simple preparation process due to no use of organo-modified silicate, thus achieving an economic benefit.

REFERENCES:
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patent: 20020055581 (2002-05-01), Lorah et al.
patent: 20020086908 (2002-07-01), Chou et al.
Choi et al., Synthesis of exfoliated polyacrylonitrile/Na-MMT nanocomposites via emulsion polymerization, Chem. Mater. 2002, vol. 14, pp 2936-2939.*
Choi et al., Synthesis of Exfoliated Polyacrylonitrile/Na-MMT Nanocomposites via Emulsion Polymerization, Chem. Mater. 2002, vol. 14, pp. 2936-2939.

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