Dehydrogenation method and nonacidic multimetallic catalytic com

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260668D, 260669R, 2606833, 252441, 252466B, 252466PT, C07C 536, C07C 1300, C07C 1500

Patent

active

041015932

ABSTRACT:
Dehydrogenatable hydrocarbons are dehydrogenated by contacting them, at dehydrogenation conditions, with a catalytic composite comprising a combination of catalytically effective amounts of a platinum or palladium component, a rhodium component and a cobalt component with a porous carrier material. A specific example of the nonacidic catalytic composite disclosed herein is a combination of a platinum or palladium component, a rhodium component, a cobalt component, and an alkali or alkaline earth component with a porous carrier material in amounts sufficient to result in a composite containing about 0.01 to about 2 wt. % platinum or palladium, about 0.01 to about 2 wt. % rhodium, about 0.05 to about 5 wt. % cobalt and about 0.1 to about 5 wt. % alkali metal or alkaline earth metal. A preferred modifying component for the disclosed catalytic composites is a Group IVA metallic component.

REFERENCES:
patent: 3576766 (1971-04-01), Rausch
patent: 3644198 (1972-02-01), Wilhelm
patent: 3775300 (1973-11-01), Hayes
patent: 3847794 (1974-11-01), Rausch
patent: 3960710 (1976-06-01), Hayes
patent: 4018669 (1977-04-01), Hayes

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