Ni/metal hydride secondary element

Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Electrode

Reexamination Certificate

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C429S209000, C429S218100

Reexamination Certificate

active

06881519

ABSTRACT:
A Ni/metal hydride secondary element having a positive nickel hydroxide electrode, a negative electrode having a hydrogen storage alloy, and an alkaline electrolyte, the positive electrode, provided with a three-dimensional metallic conductive structure, also contains an aluminum compound which is soluble in the electrolyte, in addition to nickel hydroxide and cobalt oxide. The aluminum compound is aluminum hydroxide and/or aluminum oxide, and the mass of the aluminum compound which is present in the positive bulk material mixture is 0.1 to 2% by weight relative to the mass of the nickel hydroxide which is present. In combination with aluminum hydroxide or aluminum oxide, the positive electrode further contains lanthanoid oxidic compounds Y2O3, La2O3and Ca(OH)2, as well as mixtures of these compounds.

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David Linden, “Handbook of Batteries,” second edition, McGraw-Hill, Inc., 1994.*
D.H. Buss et al.,The Electrochemical Properties of the Intercalation Compounds Cobalt Hydroxide-Aluminium Hydroxide and Nickel Hydroxide-Aluminium Hydroxide, J. Chem. Soc., Chem. Commun., 1985, pp 81-82.
Patrick Bernard,Effects on the Positive Electrode of the Corrosion of AB5Alloys in Nickel-Metal-Hydride Batteries, J. Electrochem. Soc., vol. 145, No. 2, Feb. 1998, pp 456-458.

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