Process for preparing functionalized polymer compositions

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...

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524832, 524833, 526210, 526212, 526271, 526310, 526312, 5263182, 5263183, 5263185, 526320, 526321, 5263285, 528 44, 528 59, 528 85, 528272, 5282955, 528297, 528301, 528306, 528332, 528366, 528392, 528393, C08G 6102, C08L 6500

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051303698

ABSTRACT:
Functionalized polymeric compositions are prepared by polymerizing ethylenically unsaturated functional monomer in a solvent including a reactive compound. The functional groups of the reactive compound and the functional monomer react during or subsequent to the polymerization of the functional monomer to provide functionalized polymeric composition. The reactive compound can be a hydroxy-terminated, poly(ethleneoxy)ated hydrophobe-bearing compound and the functional monomer can be a polymerizable carboxylated monomer, the functionalization in this case being a condensation. Removal of the water of condensation by azeotropic distillation drives the reaction to completion. The resulting high solids functionalized polymeric composition is soluble or dispersible in an appropriate solvent, and can be used as is, diluted with a solvent, or isolated. Polymeric compositions prepared according to the process can be used as builders in detergent compositions, as pigment dispersants in coating compositions, as tanning agents for leather, as associative thickeners and rheology modifiers for coatings compositions, and in a variety of other applications.

REFERENCES:
patent: Re23514 (1952-06-01), Voss
patent: 2820777 (1958-01-01), Suen et al.
patent: 3368999 (1968-02-01), Sekmakas et al.
patent: 3388106 (1968-06-01), Muskat
patent: 3629357 (1971-12-01), Sekmakas

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