Pyrrole stabilizers for chlorine-containing thermoplastics

Details Pyrrole stabilizers for chlorine-containing thermoplastics Pyrrole stabilizers for chlorine-containing thermoplastics

1980-06-30

1981-09-22

Anderson, Harold D.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

260 23XA, 260 457PH, 260 4575Q, 260 4575W, 2603131, C07D20732, C07D207333, C08K 534

Patent

active

042909406

ABSTRACT:
Chlorine-containing thermoplastics, containing a pyrrole of the formula I ##STR1## in which R.sub.1 is hydrogen, alkyl, cycloalkyl, aryl, alkoxycarbonylmethyl, free or esterified .alpha.-hydroxyalkyl, free or esterified .alpha.-hydroxycycloalkylmethyl, free or esterified .alpha.-hydroxyaralkyl, alkoxymethyl, alkylthiomethyl, aryloxymethyl, arylthiomethyl, cycloalkoxymethyl, cycloalkylthiomethyl, aralkoxymethyl, aralkylthiomethyl, alkoxy, alkylthio, cycloalkoxy, cycloalkylthio, aralkoxy, arylalkylthio, aryloxy, arylthio, halogen, mercapto, mercaptomethyl or hydroxyl, R.sub.2 is hydrogen, alkyl, cycloalkyl, aryl, free or esterified .alpha.-hydroxyalkyl, in which the alkyl moiety together with R.sub.1 can be alkylene, or free or esterified .alpha.-hydroxycycloalkylmethyl, free or esterified .alpha.-hydroxyaralkyl, alkoxy, cycloalkoxy, aralkoxy, aryloxy, alkylthio, cycloalkylthio, aralkylthio, arylthio, alkoxymethyl, alkylthiomethyl, aryloxymethyl, arylthiomethyl, cycloalkoxymethyl, cycloalkylthiomethyl, aralkoxymethyl, aralkylthiomethyl, hydroxyl, cyano, free carboxyl or carboxyl in the form of a salt or an ester, or acyl, it being possible for acyl together with R.sub.1 to be --CO-alkylene, in which --CO-- is bonded in the 3-position, or R.sub.2 is halogen, mercapto or mercaptomethyl, and R.sub.3 is alkyl, cycloalkyl, aralkyl, aryl, free or esterified hydroxymethyl, alkoxymethyl, alkylthiomethyl, cycloalkoxymethyl, cycloalkylthiomethyl, aralkoxymethyl, arylalkylthiomethyl, aryloxymethyl or arylthiomethyl, alkoxy, alkylthio, cycloalkoxy, cycloalkylthio, aralkoxy, aralkylthio, aryloxy, arylthio, halogen, mercapto or mercaptomethyl, or if R.sub.2 is carboxyl in the form of a salt, R.sub.3 is hydrogen and R.sub.1 is as defined, or in which R.sub.3 is hydroxyl and R.sub.1 is hydrogen, alkyl or aryl and R.sub.2 is hydrogen, alkyl, aryl or acyl, or a salt thereof.

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