Stock material or miscellaneous articles – Composite – Of aldehyde or ketone condensation product
Reexamination Certificate
2002-03-11
2004-06-15
Kiliman, Leszek B (Department: 1773)
Stock material or miscellaneous articles
Composite
Of aldehyde or ketone condensation product
C428S528000, C428S529000, C428S536000, C428S537100, C427S341000, C427S342000, C427S382000, C427S401000, C156S331900
Reexamination Certificate
active
06749949
ABSTRACT:
The present invention relates to a method of producing formaldehyde laden layered products having reduced emission of formaldehyde having at least two layers at least one of which being a board or a veneer. It also relates to a board, a veneer and a flooring material obtained by the method, to an aqueous solution comprising ammonium sulphite or bisulphite and urea for use in the method and to a process for preparation of the aqueous solution. The method, according to the present invention, comprises treatment prior to bonding the layers together of at least one of the surfaces of said board or veneer with a solution comprising an inorganic sulphur containing salt.
Aldehydes, especially formaldehyde based resins, are widely used in adhesive compositions, which are used in the manufacture of construction materials such as panelling, decking, etc.; home furnishings such as furniture, flooring material, etc. Typically, these adhesives compositions contain a substantial molar excess of formaldehyde. Some of this excess formaldehyde is released upon curing of the resin during the manufacture of the product. However, it is well known that formaldehyde continues to be released from these products even after the manufacturing process is completed. Thus, formaldehyde in the indoor air has been a major concern for many years.
Several attempts have been made for many years for reducing formaldehyde emission, but all entail significant mechanical, chemical, environmental or economical disadvantages.
EP 0 027 583 discloses a method of reducing the emission of formaldehyde from particleboard bound with carbamide resin. The boards are treated with a thermally decomposable ammonium compound, such as ammonium carbonate, subsequent to pressing. The thus treated boards are then stacked and stored at temperatures from 40 to 70° C., so that ammonia can be released.
Moreover, layered flooring material, such as three-layer parquet floor can emit formaldehyde due to the different wood layers being normally bonded together by gluing with formaldehyde based adhesives. The top layer usually consists of hardwood, the middle layer of softwood or a board, for example, MDF, HDF or particle board and the bottom layer of a veneer. The top layer is usually treated with a formaldehyde free UV-lacquer or an oil to protect the surface, which also may function as a barrier to the formaldehyde emission. The different parts of a parquet sample, such as the front, the back, and the edges, give different emission rates. For example, the formaldehyde emission from the backside can be 20 times higher than that from the front side.
Furthermore, there is an increasing demand for parquet flooring which can meet the required E1 value obtained in a chamber test according to the Swedish standard SS 270236 (SS 1988). In cases where the emission test for parquet flooring has been performed with samples having unexposed backsides and sealed edges, the obtained emission values have been very low, often under 0.05 mg/m
3
(the limit value for E1 being 0.13 mg/m
3
).
Additionally, there is proposed a new European standard, EN 717-1, for formaldehyde emission determination, according to which all samples to be measured will have exposed backside and partially exposed edges. This makes it more difficult for the flooring producers to achieve extremely low formaldehyde emission values.
Furthermore, there will be demands on meeting the Japanese standard JAS SIS20, which involves a desiccator measurement where the backside and the edges of the sample cannot be sealed, but they are totally exposed.
Thus, technical solutions are still sought for the need to decrease the emission of formaldehyde from wood-based products containing formaldehyde-based resins, meeting the new more strict standards for formaldehyde emission from these products.
Accordingly, the present invention provides a method of producing wood-based products containing formaldehyde based resins having reduced emission of formaldehyde from, by which the above mentioned problems are overcome.
The method according to the invention comprises treatment of at least one of the surfaces of a board or veneer, comprised in a layered product having at least two layers, prior to bonding the layers together, with a solution comprising an inorganic sulphur containing salt.
By “formaldehyde laden layered products” is herein meant a layered product containing formaldehyde based resins, wherein the layers are bonded to each other by a formaldehyde based adhesive and in case one or more of the layers is a board that the board as such may also be bonded with a formaldehyde based adhesive.
Suitably, the concentration of the inorganic sulphur containing salt in the solution is from about 1 to about 30 weight %, preferably from about 5 to about 20 weight %, and most preferably from about 8 to about 13 weight %. Although application of the salt in the form of a solution is preferred, according to the invention, it may also be applied in the form of a powder, if so desired. For environmental reasons, the solution is suitably an aqueous solution, although other solvents than water may be used. The salt solution may be applied by using any conventional coating technique, such as roller coating, curtain coating, or, spray coating. The amount of salt solution applied, when only one of the surfaces is treated, is suitably from about 30 to about 90 g/m
2
, preferably from about 40 to about 80 g/m
2
, and most preferably from about 55 to about 65 g/m
2
. If both of the surfaces are to be treated, then the applied amount per side is suitably half of the amount if only one of the surfaces would be treated. In order to avoid disturbance of the moisture balance of the treated product large amounts of salt solution are undesirable.
The inorganic sulphur salts according to the invention have a very high water-solubility, whereas carbonate salts have a rather limited water-solubility. Thus, in order to obtain an effective salt solution resulting in the desired reduction of formaldehyde emission, a larger amount of carbonate salt solution comparing to that of sulphite salt solution, is required to be applied onto the surface to be treated, which can affect negatively the moisture balance of the treated product and therefore even of the finished layered product.
Moreover, the inorganic sulphur salts according to the invention do not discolour the finished layered product, especially its outer surface, whereas carbonate salts may have a discolouring effect on the outer layer of the finished product and especially on oak surfaces.
Suitable inorganic sulphur containing salts include sulphite or bisulphite salts such as, for example, alkali metal sulphites or bisulphites or ammonium sulphites or bisulphites. Water-soluble sulphite or bisulphite salts are preferred. Preferably, ammonium sulphite or bisulphite is used, and most preferably ammonium sulphite.
The method of reducing the amount of formaldehyde liberated by materials and products prepared with formaldehyde based resins is applicable to all formaldehyde based resins, for example, it is applicable to urea-formaldehyde, melamine-formaldehyde, phenol-formaldehyde resins and the like as well as copolymers, blends and mixtures made therefrom.
In a preferred embodiment of the invention, urea is added to the inorganic sulphur containing salt solution. Even though the inorganic sulphur containing salt does alone effectively reduce the emission of formaldehyde, the addition of urea to the salt solution improves further the reduction of formaldehyde emission. Suitably, the weight ratio of urea to sulphur-containing salt is from about 1:10 to about 1:1, preferably from about 2:10 to about 8:10, and most preferably from about 3:10 to about 6:10.
The board to be treated according to the invention may be any kind of board such as particle board, chip board, or, fibre board, and it may be bound with adhesives based on formaldehyde based resins or other non-formaldehyde based resins.
The veneer to be treated according to the invention may be any kind of wood veneer, prefera
Lindh Ingvar
Ljungar Robin
Pirhonen Salme
Akzo Nobel N.V.
Kiliman Leszek B
Serbin David J.
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