Electric lamp and discharge devices – With luminescent solid or liquid material – With gaseous discharge medium
Reexamination Certificate
2001-05-09
2004-09-07
Martin, David (Department: 2841)
Electric lamp and discharge devices
With luminescent solid or liquid material
With gaseous discharge medium
Reexamination Certificate
active
06787979
ABSTRACT:
BACKGROUND OF THE INVENTION
The invention relates to a rare-gas low-pressure discharge lamp, a method of manufacturing a rare-gas low-pressure discharge lamp, and various applications of a gas discharge lamp, in particular for cosmetic or therapeutic purposes.
Rare-gas low-pressure discharge lamps are known. They serve, for example, for background lighting of LCD displays. In addition, WO 98/19327 discloses a xenon lamp which generates light with strictly limited spectral lines for certain therapeutic purposes. This lamp, however, is not suitable for wide application ranges, in particular as a suntanning lamp in solariums.
Known suntanning lamps are on the one hand mercury low-pressure gas discharge lamps provided with one or two phosphors, or high-pressure mercury vapor discharge lamps without phosphor. Both types of lamps emit mainly in the UV-A range. It is advantageously possible in the case of lamps with phosphors to adjust the UV-A spectrum by means of the composition of the phosphor, but on the other hand both lamps disadvantageously contain highly toxic mercury, which means that they have to be disposed of with great care.
The suntanning results obtained with these lamps, in particular the skin color and the permanence of the suntanning effect, depend mainly on the spectral power distribution of the UV source, because both reddening of the skin (erythema) and the immediate and delayed pigment formation show a strong dependence on the wavelength of the radiated UV light. Accordingly, an additional UV-B phosphor is added in several lamp types so as to modify the spectrum of the lamps in a desired manner. The spectrum of the lamps is usually identified by means of the following ratios: UV-B / UV-A, UV-A
1
/ UV-A
2
, and erythema B / erythema A. The quantities usually vary within the following wavelength ranges: UV-A
1
=340 to 400 nm, UV-A
2
=320 to 340 nm, erythema B=280 to 320 nm, erythema A=320 to 400 nm, UV-B=280 to 320 nm.
Lamps were developed recently whose phosphor compositions are based on a mixture of LaPO
4
:Ce (LAP for short) and BaSi
2
O
5
:Pb (BSP). These lamps show an erythema efficiency spectrum which is very similar to that of the sun.
Although major steps forward have been made in the field of suntanning lamps, they still have a number of disadvantages which are directly linked to the use of the mercury plasma. Thus, for example, a few spectral lines of the mercury plasma lie in the UV range (297, 312.5, and 365 nm), and a few lie in the visible range (405, 435, 546, and 579 nm). The presence of these visible mercury lines gives the light of these lamps a bluish appearance, which is not appreciated by the customers. The mercury vapor lines in the UV range in addition interfere with the free adjustability of the UV spectrum by means of the phosphor and are to be taken into account in the calculation of the specification parameters of such a lamp.
A further disadvantage is the low stability of these lamps. Thus, for example, the interaction of the mercury with certain phosphors, for example BSP, leads to a UV-absorbing layer which strongly reduces the UV efficacy during lamp life. In addition, the desired UV light is not immediately available because of the starting behavior of the lamps. Finally, the lamp geometry is limited to tubular shapes, so that a field of lamps arranged next to one another is to be used in order to obtain a suitable light distribution over a larger surface area such as, for example, in a suntanning couch. Even though several lamps are arranged next to one another, a perfectly homogeneous light distribution is never obtained.
OBJECTS AND SUMMARY OF THE INVENTION
The invention accordingly has for its object to provide a lamp of the kind mentioned in the opening paragraph and a method of manufacturing such a lamp which are particularly suitable for cosmetic and therapeutic purposes, rendering it possible to utilize the advantages of a rare-gas low-pressure discharge lamp for generating UV light of a certain spectral range.
This object is achieved by means of a rare-gas low-pressure discharge lamp with a discharge vessel which is filled with a rare gas and is at least partly transparent to UV light, wherein the discharge vessel is at least partly coated with a phosphor which radiates UV light when excited by an excitation light produced in the discharge vessel.
A major advantage of such a lamp is that light of the desired type can be available immediately after ignition, whereas in mercury vapor discharge lamps the mercury is to be evaporated first. A further advantage of the lamp is its very long useful life, usually more than 20,000 hours of operation. In addition, the lamp is environmentally friendly because it does not contain any toxic mercury.
A rare gas such as, for example, xenon or neon emitting exclusively in the VUV and/or UV-C range can be used in the discharge vessel because a UV source with a broadband emission in the range from 290 to 400 nm without additional plasma emission lines in the UV and/or visible range is desired for suntanning purposes. It may also be useful to use a mixture of these two gases. The generated short wavelengths may then be converted into suitable UV-A and/or UV-B light by one phosphor or a mixture of several phosphors. This has the advantage that no plasma lines are in the visible range, so that the light radiated by the lamp is not perceived as unpleasant by the user.
In a preferred embodiment of the invention, the discharge vessel is at least partly made of a glass, preferably of a glass having a transmissivity of 20 to 70% for light of 312.6 nm wavelength.
The invention advantageously enables the manufacture of a lamp in which the spectral power distribution depends only on the phosphor or phosphor mixture used. It was found to be particularly advantageous when a phosphor or a combination or mixture of several phosphors is used in which less than 1% of the light radiated thereby upon excitation by an excitation light produced in the discharge vessel has wavelengths below 290 nm, between 1% and 10% of the radiated light has wavelengths between 290 and 320 nm, and less than 5% of the radiated light has wavelengths above 400 nm.
Such radiation properties allow of the use of, for example, phosphors or combinations of phosphors such as BaSi
2
O
5
:Pb (BSP for short), CeMgAl
11
O
19
(CAM), LaPO
4
:Ce (LAP), SrB
4
O
7
:Eu (SBE), and (Sr,Ba)MgSi
2
O
7
:Pb (SMS). These phosphors have a high efficacy when excited by VUV, in particular in the range from 140 to 190 nm in which the rare-gas discharge lamps mainly emit, and their emission bands lie in the UV-A and/or UV-B range, each with a comparatively small width, so that the emission can be concentrated in one range in which, for example, the suntanning efficacy is particularly high. The use of a combination of a UV-B phosphor, for example LAP, and a UV-A phosphor, for example BSP, renders it possible to adjust the specification parameters of the lamp such that the desired approximation of a given desired spectrum is achieved.
Since the light generated by the lamp should as a rule be radiated in a preferred direction, a UV-light reflecting layer, in particular a layer comprising MgO and/or Al
2
O
3
, may be provided on portions of the discharge vessel so that the high-energy UV light generated in the discharge vessel can be guided to certain portions of the discharge vessel at which it is to be converted into low-energy UV light, such that the lamp has a very high efficacy and a correspondingly high suntanning power.
The lamp according to the invention advantageously enables a completely new, free design of the lamp geometry, in particular in the case of suntanning lamps, which may be, for example, curved or planar, whereas the familiar mercury vapor discharge lamps always had to be tubular in shape. Thus it becomes possible to adapt the discharge vessel to the contours of a surface to be irradiated by the lamp.
In addition, the invention proposes a corresponding manufacturing process for such a lamp. Here, in particu
Jalink Cornelis Jojakim
Juestel Thomas
Nikol Hans
Bartlett Ernestine C.
Martin David
Phan Thanh S.
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