Plastic and nonmetallic article shaping or treating: processes – Mechanical shaping or molding to form or reform shaped article – Shaping against forming surface
Reexamination Certificate
2000-06-19
2004-01-27
Staicovici, Stefan (Department: 1732)
Plastic and nonmetallic article shaping or treating: processes
Mechanical shaping or molding to form or reform shaped article
Shaping against forming surface
C264S311000, C264S319000, C524S502000, C524S515000, C525S171000, C525S240000
Reexamination Certificate
active
06682685
ABSTRACT:
FIELD OF THE INVENTION
This invention relates to a method of rotational molding using a unique resin blend and to the resulting molded objects.
BACKGROUND OF THE INVENTION
Rotational molding is, in theory, a very straightforward process. To make an object using rotational molding, all that is required are: (1) a mold to hold the material in the configuration desired when the processing is complete; (2) a source of heat to melt the resin or plastic under control conditions; (3) a machine to distribute the material uniformly over the surface of the mold; and (4) a method of cooling the resin under controlled conditions.
There are several advantages which may be derived using rotational molding. The tooling costs are economical and a hollow, one-piece object results which is virtually stress-free. Uniform wall thicknesses can be provided, and there is substantial design flexibility, allowing molding of hollow, one-piece objects ranging from relatively small objects to intricate designs and to large and complex shapes.
Common rotationally molded products include, as illustrative examples, shipping drums, storage tanks and receptacles, material handling bins, and housings. Consumer products made using rotational molding range from furniture to toys and to marine accessories.
However, there are a variety of problems, difficulties and/or complications involved when using rotational molding. One significant problem derives from the process itself. The resin which is the standard commercially available is provided in relatively large-sized particles, typically in the form of pellets. The current result is that resin producers typically manufacture resins with a pellet size ranging from 35 to 60 pellets/gram. As hereinafter discussed, particles of this size do not process well given the processes currently being used by rotational molders. Accordingly, such relatively large pellets are ground to provide powders ranging from 22 mesh up to about 35 or even 50 mesh. The grinding processes involved typically result in a relatively wide bell-shaped particle distribution curve. In the rotomolding cycle, the smaller ground particles melt first, much like ground ice melts faster than ice cubes.
While such finely ground powder is widely used in the rotomolding process to achieve this faster melting quality, the use of such ground powder presents several problems. The particle size distribution achieved following grinding varies widely from one grinder to another. Indeed, sometimes the distribution curve will vary significantly even when the same grinder is used, such as, for example, which can occur when the mechanical set-up conditions are altered slightly. This variation in the particle size distribution will effect the delivery system in the rotomolding process which can cause variations in the wall thickness of the object being molded. Further, the grinding process adds not only significant expense, but can lead to inventory problems simply because of the volume of resin needed to be ground.
Still further, and importantly, the fines in such ground resin can create processing and housekeeping problems, simply due to the level of dust involved. Such resulting dust can likewise create a potential safety issue.
Yet, despite the continuing need for a solution to these very real problems, no solution exists insofar as the present inventor is aware. Rather, the resin source used in rotomolding continues to be ground powder.
SUMMARY OF THE INVENTION
In general, the present invention is predicated on the discovery that a resin blend capable of achieving rotationally molded parts having impact strength and other characteristics, similar to that achieved with ground resin powder, can be obtained by eliminating much of the ground resin powder previously considered essential. More particularly, it has been found that rotationally molded parts having adequate processing and strength and other product characteristics can be obtained utilizing a blend of resin pellets in the size range obtained from the resin manufacturer while utilizing only a minor amount of ground powder.
Thus, as one example, when using a rotomold grade of polyethylene, rotomolded parts made from a resin blend containing only 20% to 50% ground resin powder and the balance resin pellets achieve low temperature impact strength characteristics essentially the same as those achieved with a rotomolded part made entirely from ground powder. This is particularly surprising, perhaps evidencing some synergistic processing and/or other properties, in view of the dramatic drop-off in properties that result when the ground powder component is reduced to 10% or less.
The present invention provides a method of rotational molding using a resin blend which avoids the problems of prior rotational molding techniques that employ ground resin powder. These and other advantages of the present invention, as well as additional inventive features, will be apparent from the description of the invention provided herein.
DETAILED DESCRIPTION OF THE INVENTION
Typically, resins such as LLDPE resins (linear low-density polyethylene) are currently manufactured in a standard commercial pellet count of about 35 to 60 pellets/gram, as previously noted. While such pellets may be utilized to create rotationally molded parts, it has been found that such relatively large sized pellets will provide undesirable properties for direct use in rotationally molding, including the fabrication of composite laminates because of the melting and coalescence characteristics of such larger pellets. More particularly, composite laminates can be molded using different polymers or the same polymer with different physical properties and/or characteristics. The pellet size affects the ability of the polymer to melt out and achieve optimum particle coalescence. The molding process, including the selection of polymer having an appropriate particle size, is intended to achieve optimum adhesive and physical properties both within and between the composite laminate materials. However, as will be discussed hereinafter, the present invention utilizes a blend comprising predominantly such resin pellets.
Any type of resin used in conventional rotational molding may be utilized. The particular resin selected will be determined by the requirements for the object or part being rotationally molded. Currently, the most common resin used is polyethylene. Many types of polyethylene are commercially available, with a wide range of properties and all may be used. In general, the types of polyethylene available can be described as linear low-density polyethylene, low-density polyethylene, medium-density polyethylene, and high-density polyethylene. Still further, each material type is manufactured using unique technology to achieve desired material physical characteristics and properties. Examples of these are hexene, butene, and metallocene molecular chains used in resin technologies.
In addition, other polyolefins are known and may be used including, for example, polypropylene. Further, ethylene-vinyl acetate resins can be used.
Still further illustrative examples of other types of resins useful in the method of this invention include polycarbonates, nylons, polyvinylchlorides, and polyesters. Additional useful resins include ABS, acetals, acrylics, cellulosics, epoxies, fluorocarbons, phenolics, polystyrenes, polyurethanes, SAN polymers, and silicone polymers. Mixtures of any of the various resins discussed herein may also be used.
Typically, any useful colorants may be used to provide the desired colors for the particular product being molded. Any heat stable and unreactive colorants known and available for use for the particular resins may be employed. As illustrative examples, virtually any color can be provided, ranging from white to yellow, red, orange, green, burgundy and black.
Illustrative examples of useful colorants include titanium dioxide, carbon black, iron oxide, ultramarine blue, cadmium sulfide, phthalocyanine green, phthalocyanine blue, chromium oxide, quinacridone red, anthraquinone and per
Chroma Corporation
Staicovici Stefan
LandOfFree
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