Electric lamp and discharge devices – With gas or vapor – Electrode composition
Reexamination Certificate
2000-11-20
2004-01-06
Glick, Edward J. (Department: 2882)
Electric lamp and discharge devices
With gas or vapor
Electrode composition
C313S311000
Reexamination Certificate
active
06674240
ABSTRACT:
FIELD OF THE INVENTION
The invention relates to a gas discharge lamp, in particular a low-pressure gas discharge lamp, which comprises an electrode including a carrier of an electrode metal and an electrode coating of an electron-emitting material, which material comprises a metal powder and at least one alkaline earth oxide selected from the group formed by calcium oxide, strontium oxide and barium oxide.
BACKGROUND OF THE INVENTION
The generation of light in a gas discharge lamp is based on the ionization, and the resulting electric discharge, of the atoms of the filling gas in the lamp when an electric current flows through the lamp. The electrodes of the lamp emit electrons, which are so strongly accelerated by the electric field between the electrodes that, upon colliding with the gas atoms, they are capable of exciting and ionizing the latter. When the gas atoms return to the ground state, as in the case of the recombination of electrons and ions, a more or less substantial part of the potential energy is converted to radiation.
The amount of electrons that can be emitted by the electrodes depends upon the work function of the electrodes for electrons. Tungsten, which is customarily used as the electrode metal, has itself a comparatively high work function. For this reason, the electrode metal is customarily coated with a material which mainly serves to improve the electron-emitting properties of the electrode metal. It is typical of the electron-emitting coating materials of electrodes in gas discharge lamps that they contain an alkaline earth metal, either in the form of the alkaline earth metal oxide or in the form of an alkaline earth metal-containing starting compound (precursor) for the alkaline earth metal oxide.
Thus, conventional low-pressure gas discharge lamps are generally provided with electrodes which are composed of tungsten wires with an electron-emitting coating containing oxides of the alkaline earth metals calcium, strontium and barium. To manufacture such an electrode, a tungsten wire is coated, for example, with the carbonates of the alkaline earth metals in a binder preparation. During evacuating and baking out the lamp, the carbonates are converted into the oxides at temperatures of approximately 1000° C. After this burn-off of the electrode, the electrode already supplies a noticeable emission current which, however, is not stable yet. Next, an activation process is carried out. As a result of this activation process, the originally non-conducting ion lattice of the alkaline earth oxides is converted to an electronic semiconductor by incorporating donor-type imperfections into the crystal lattice of the oxides. These imperfections essentially consist of elementary alkaline earth metal, for example calcium, strontium or barium. The electron emission of such electrodes is based on this mechanism of imperfections. The activation process serves to provide a sufficient quantity of excess, elementary alkaline earth metal, enabling the oxides in the electron-emitting coating to supply as much emission current as possible at a prescribed heating capacity.
As regards the function of these electrodes and the service life of the lamp, it is important that elementary alkaline earth metal is constantly available. The reason for this being that the electrode coating continuously loses alkaline earth metal during the service life of the lamp, which is partly caused by the fact that the electrode coating evaporates slowly, and partly by the fact that the electrode coating is sputtered off by the ionic current in the lamp.
The elementary alkaline earth metal is initially dispensed continuously by a reduction of the alkaline earth oxide at the tungsten wire during operation of the lamp. However, this dispensation stops when the tungsten wire is passivated, in the course of time, by a high-impedance interface of tungsten oxide, alkaline earth silicate or alkaline earth tungstate.
To improve the reduction of barium oxide to elementary barium in a fluorescent lamp, it is known from DE 44 15 748 that the electron-emitting substance comprises, in addition to alkaline earth mixed carbonate and zirconium oxide, 3 to 15 wt.% of a reducing metal powder having a high melting point, said reducing metal powder being selected from at least one metal of the group composed of tantalum, niobium, tungsten and molybdenum, and the electron-emitting substance is distributed such that it fills the whole winding core of the coil including the two terminal windings of the multi-section coil of incandescent wire.
However, like the electrode carrier wire, the metal powders of tantalum, niobium, tungsten or molybdenum are surrounded in the course of time with a passivating interface of tungsten oxide, alkaline earth silicate or alkaline earth tungstate, or of the corresponding niobium, tantalum or molybdenum compounds.
SUMMARY OF THE INVENTION
It is an object of the present invention to provide a gas discharge lamp with an extended service life and an improved emission current.
In accordance with the invention, this object is achieved by a gas discharge lamp comprising an electrode including a carrier of an electrode metal and a first electrode coating of an electron-emitting material, which material comprises a metal powder preparation of a powder of a reducing metal selected from the group formed by aluminum, silicon, titanium, zirconium, hafnium, tantalum, molybdenum, tungsten and the alloys thereof, which metal powder preparation is provided with a powder coating containing a noble metal selected from the group formed by rhenium, cobalt, nickel, ruthenium, palladium, rhodium, iridium and platinum, and the alloys thereof, and said material comprising at least one alkaline earth metal oxide selected from the group formed by calcium oxide, strontium oxide and barium oxide.
Gas discharge lamps comprising such electrodes exhibit a uniform electron emission for a long period of time, because the powder coating on the metal powder containing a noble metal causes a reaction between the alkaline earth oxide and the reducing metal to be precluded during the activation phase in the course of the manufacture of the gas discharge lamp. The reducing metal only diffuses through the powder coating of a noble metal, thereby reducing the alkaline earth oxide to elementary alkaline earth metal, when the gas discharge lamp is in operation. As a result of continuous alkaline earth dispensation, exhaustion of the electron emission is precluded, and the release of metallic alkaline earth in a sufficient quantity during the entire operation of the lamp is ensured. The emission current is homogeneous and uniform, and the service life of the gas discharge lamp is extended.
The electrodes used in these gas discharge lamps are also resistant to poisoning. The reject rate in the manufacturing process is small as these electrodes can be manufactured in a readily reproducible manner.
In accordance with a preferred embodiment of the gas discharge lamp, a second electrode coating of a noble metal selected from the group formed by rhenium, cobalt, nickel, ruthenium, palladium, rhodium, iridium, platinum is arranged between the carrier and the first electrode coating. Such a gas discharge lamp has a reduced ignition time, the electrode accommodated in such a lamp has a low work function and an improved conductivity.
It may be preferred that the metal powder preparation is made from a powder of a tungsten-iridium alloy with a powder coating of iridium.
It may also be preferred that the electron-emitting material additionally comprises zirconium oxide.
In accordance with another preferred embodiment, the metal powder preparation has an average grain size d in the range from 2.0 &mgr;m≦d≦3.0 &mgr;m.
These and other aspects of the invention will be apparent from and elucidated with reference to the embodiment(s) described hereinafter.
REFERENCES:
patent: 5654606 (1997-08-01), Weijtens et al.
patent: 5847498 (1998-12-01), Mehrotra et al.
patent: 4415748 (1995-11-01), None
Gärtner Georg
Van Den Hoek Wilem Jacobus
Gemmell Elizabeth
Glick Edward J.
Keegan Frank J.
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